X-ray absorption near edge structure simulation of LiNiCoMnO first-principles calculation.

Simulation of Ni K-edge X-ray absorption near edge structure (XANES) spectra in LiNiCoMnO (NCM523) was performed. The structure of NCM523 was optimized by first-principles calculation based on density functional theory and XANES spectrum simulation the finite difference method. The calculated Ni K-edge XANES spectra of NCM523 with Li amounts of 1.0 and 0.5 showed good agreement with the measured spectra. The bond length between Ni and O shortened as the valence of Ni increased. Distortion of the structure resulting from Jahn-Teller distortion was observed with Ni. The XANES spectra of the Ni K-edge of Ni, Ni, and Ni were calculated. In NCM523 with a Li amount of 1.0, the spectrum of Ni shifts towards the higher energy side compared to that of Ni; at a Li amount of 0.5 the absorption edge of Ni, Ni, and Ni shifts toward a higher energy as valence increases. Even at the same Ni valence number, the XANES spectra were different when the Li amounts were 1.0 and 0.5. Cation mixing of Li/Ni readily occurs at a Li amount of 1.0, more than that of 0.5 because of the super exchange interaction. The K-edge XANES spectrum of the Ni of the Li site did not change the position of the absorption edge of the Ni site Ni XANES spectrum; a difference in shape of the shoulder peak and the pre-edge peak appeared. From these results, the Ni valence, bonding state, and cation mixing effect of Li/Ni on the Ni K-edge XANES spectrum in NCM523 were clarified.