Andrea Kori A, Kerton Francesca M
Department of Chemistry, Memorial University of Newfoundland St. John's NL A1B 3X7 Canada
RSC Adv. 2019 Aug 23;9(46):26542-26546. doi: 10.1039/c9ra05947d.
Triphenylborane catalyzes the copolymerization and terpolymerization of epoxides and CO to yield polycarbonates with excellent dispersity. assisted tandem catalysis, these materials could be hydrosilylated in a one-pot fashion yielding modified polymeric materials. Using only a few reagents, materials with glass transition temperatures ranging from 37-110 °C were obtained.
三苯基硼烷催化环氧化物与一氧化碳的共聚和三元共聚反应，以生成具有优异分散性的聚碳酸酯。通过辅助串联催化，这些材料可以一锅法进行硅氢化反应，生成改性聚合物材料。仅使用几种试剂，就获得了玻璃化转变温度范围为37至110°C的材料。
