• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

电沉积在电化学还原氮掺杂氧化石墨烯/碳陶瓷电极上的镍钴合金纳米颗粒：一种用于甲醇和乙醇氧化的低成本电催化剂。

NiCo alloy nanoparticles electrodeposited on an electrochemically reduced nitrogen-doped graphene oxide/carbon-ceramic electrode: a low cost electrocatalyst towards methanol and ethanol oxidation.

作者信息

Rahmani Kaveh, Habibi Biuck

机构信息

Electroanalytical Chemistry Laboratory, Department of Chemistry, Faculty of Sciences, Azarbaijan Shahid Madani University Tabriz 53714-161 Iran

出版信息

RSC Adv. 2019 Oct 23;9(58):34050-34064. doi: 10.1039/c9ra06290d. eCollection 2019 Oct 18.

DOI:10.1039/c9ra06290d
PMID:35528884
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9073643/
Abstract

In this work, nickel-cobalt alloy nanoparticles were electrodeposited on/in an electrochemically reduced nitrogen-doped graphene oxide (ErN-GO)/carbon-ceramic electrode (CCE) and the resulting nanocomposite (NiCo/ErN-GO/CCE) was evaluated as a low cost electrocatalyst for methanol and ethanol electrooxidation. Field-emission scanning electron microscopy coupled with energy dispersive X-ray spectroscopy, X-ray diffraction, and Fourier-transform infrared spectroscopy were used for the physical characterization of the electrocatalyst. To study the electrochemical behavior and electrocatalytic activity of the prepared electrocatalyst towards the oxidation of methanol and ethanol in alkaline media, cyclic voltammetry, chronoamperometry and electrochemical impedance spectroscopy were utilized. Electrochemical investigation of the introduced electrocatalysts (NiCo alloy and Ni nanoparticles alone electrodeposited on/in different substrates) indicated that NiCo/ErN-GO/CCE has highest activity and stability towards methanol ( = 88.04 mA cm) and ethanol ( = 64.23 mA cm) electrooxidation, which highlights its potential use as an anodic material in direct alcohol fuel cells.

摘要

在本工作中，将镍钴合金纳米颗粒电沉积在电化学还原的氮掺杂氧化石墨烯（ErN-GO）/碳陶瓷电极（CCE）上/内，并将所得的纳米复合材料（NiCo/ErN-GO/CCE）评估为用于甲醇和乙醇电氧化的低成本电催化剂。采用场发射扫描电子显微镜结合能量色散X射线光谱、X射线衍射和傅里叶变换红外光谱对该电催化剂进行物理表征。为了研究制备的电催化剂在碱性介质中对甲醇和乙醇氧化的电化学行为和电催化活性，采用了循环伏安法、计时电流法和电化学阻抗谱。对引入的电催化剂（单独电沉积在不同基底上/内的NiCo合金和Ni纳米颗粒）进行的电化学研究表明，NiCo/ErN-GO/CCE对甲醇（ = 88.04 mA cm）和乙醇（ = 64.23 mA cm）电氧化具有最高的活性和稳定性，这突出了其作为直接醇类燃料电池阳极材料的潜在用途。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/d2d0c4bb10ed/c9ra06290d-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/464bb2a49aab/c9ra06290d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/f4970d26ae7a/c9ra06290d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/3c0b113cec88/c9ra06290d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/b8236c536e5b/c9ra06290d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/aa247f299a43/c9ra06290d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/209581e30d6d/c9ra06290d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/2dadee62a7a1/c9ra06290d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/2c14e27822dd/c9ra06290d-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/8d2433b76955/c9ra06290d-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/d0d782ec1abf/c9ra06290d-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/f2514ad455d0/c9ra06290d-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/d43ff326eaba/c9ra06290d-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/d2d0c4bb10ed/c9ra06290d-f13.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/464bb2a49aab/c9ra06290d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/f4970d26ae7a/c9ra06290d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/3c0b113cec88/c9ra06290d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/b8236c536e5b/c9ra06290d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/aa247f299a43/c9ra06290d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/209581e30d6d/c9ra06290d-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/2dadee62a7a1/c9ra06290d-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/2c14e27822dd/c9ra06290d-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/8d2433b76955/c9ra06290d-f9.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/d0d782ec1abf/c9ra06290d-f10.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/f2514ad455d0/c9ra06290d-f11.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/d43ff326eaba/c9ra06290d-f12.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80e0/9073643/d2d0c4bb10ed/c9ra06290d-f13.jpg

相似文献

1
NiCo alloy nanoparticles electrodeposited on an electrochemically reduced nitrogen-doped graphene oxide/carbon-ceramic electrode: a low cost electrocatalyst towards methanol and ethanol oxidation.电沉积在电化学还原氮掺杂氧化石墨烯/碳陶瓷电极上的镍钴合金纳米颗粒：一种用于甲醇和乙醇氧化的低成本电催化剂。
RSC Adv. 2019 Oct 23;9(58):34050-34064. doi: 10.1039/c9ra06290d. eCollection 2019 Oct 18.
2
One - Step synthesis of nitrogen doped reduced graphene oxide with NiCo nanoparticles for ethanol oxidation in alkaline media.一步法合成氮掺杂还原氧化石墨烯负载镍钴纳米粒子用于碱性介质中乙醇氧化。
J Colloid Interface Sci. 2016 Jan 15;462:148-53. doi: 10.1016/j.jcis.2015.09.072. Epub 2015 Oct 22.
3
Ru-Ni nanoparticles electrodeposited on rGO/Ni foam as a binder-free, stable and high-performance anode catalyst for direct hydrazine fuel cell.沉积在rGO/泡沫镍上的钌-镍纳米颗粒作为直接肼燃料电池的无粘结剂、稳定且高性能的阳极催化剂。
Heliyon. 2023 Jun 1;9(6):e16888. doi: 10.1016/j.heliyon.2023.e16888. eCollection 2023 Jun.
4
Hierarchical N-doped carbon nanofiber-loaded NiCo alloy nanocrystals with enhanced methanol electrooxidation for alkaline direct methanol fuel cells.具有增强的甲醇电氧化性能的分级 N 掺杂碳纳米纤维负载 NiCo 合金纳米晶，用于碱性直接甲醇燃料电池。
J Colloid Interface Sci. 2023 Sep 15;646:43-53. doi: 10.1016/j.jcis.2023.05.030. Epub 2023 May 9.
5
Reduced graphene oxide (RGO)-supported NiCo₂O₄ nanoparticles: an electrocatalyst for methanol oxidation.还原氧化石墨烯（RGO）负载的NiCo₂O₄纳米颗粒：一种用于甲醇氧化的电催化剂。
Nanoscale. 2014 Sep 21;6(18):10657-65. doi: 10.1039/c4nr02370f. Epub 2014 Aug 4.
6
Microwave-Assisted Synthesis of Highly Dispersed PtCu Nanoparticles on Three-Dimensional Nitrogen-Doped Graphene Networks with Remarkably Enhanced Methanol Electrooxidation.微波辅助合成高度分散的 PtCu 纳米粒子在三维氮掺杂石墨烯网络上，显著增强甲醇氧化。
ACS Appl Mater Interfaces. 2016 Dec 14;8(49):33673-33680. doi: 10.1021/acsami.6b11800. Epub 2016 Nov 30.
7
Electrocatalytic Performance of MnMoO-rGO Nano-Electrocatalyst for Methanol and Ethanol Oxidation.MnMoO-rGO 纳米电催化剂对甲醇和乙醇氧化的电催化性能。
Molecules. 2023 Jun 7;28(12):4613. doi: 10.3390/molecules28124613.
8
Electrocatalytic Oxidation of Methanol, Ethanol, and Glycerol on Ni(OH) Nanoparticles Encapsulated with Poly[Ni()] Film.聚[Ni()]膜包裹的Ni(OH)纳米颗粒上甲醇、乙醇和甘油的电催化氧化
ACS Appl Mater Interfaces. 2019 Aug 28;11(34):30810-30818. doi: 10.1021/acsami.9b08441. Epub 2019 Aug 14.
9
Three-Dimensional Nitrogen-Doped Reduced Graphene Oxide-Carbon Nanotubes Architecture Supporting Ultrafine Palladium Nanoparticles for Highly Efficient Methanol Electrooxidation.三维氮掺杂还原氧化石墨烯-碳纳米管结构负载超细钯纳米颗粒用于高效甲醇电氧化
Chemistry. 2015 Nov 9;21(46):16631-8. doi: 10.1002/chem.201502804. Epub 2015 Sep 25.
10
Nitrogen Doped Graphene Supported Pt Nanoflowers as Electrocatalysts for Oxidation of Formaldehyde.氮掺杂石墨烯负载的铂纳米花作为甲醛氧化的电催化剂
J Nanosci Nanotechnol. 2017 Feb;17(2):1092-098. doi: 10.1166/jnn.2017.12643.

引用本文的文献

1
Electrocatalytic Properties and DFT Studies of Pd-Based Catalysts Supported on Ceria/Onion-like Carbon for Isopropanol Oxidation in Alkaline Medium.氧化铈/洋葱状碳负载的钯基催化剂在碱性介质中对异丙醇氧化的电催化性能及密度泛函理论研究
J Phys Chem C Nanomater Interfaces. 2025 Jul 23;129(31):14214-14228. doi: 10.1021/acs.jpcc.5c03686. eCollection 2025 Aug 7.
2
Fabrication and characterization of NiCu/GO and NiCu/rGO nanocomposites for fuel cell application.用于燃料电池应用的NiCu/GO和NiCu/rGO纳米复合材料的制备与表征
RSC Adv. 2024 Feb 23;14(10):6776-6792. doi: 10.1039/d3ra07822a. eCollection 2024 Feb 21.
3

本文引用的文献

1
Synthesis of Bimetallic Ni-Cr Nano-Oxides as Catalysts for Methanol Oxidation in NaOH Solution.双金属Ni-Cr纳米氧化物作为NaOH溶液中甲醇氧化催化剂的合成
J Nanosci Nanotechnol. 2015 May;15(5):3743-9. doi: 10.1166/jnn.2015.9528.
2
Design Principles for Heteroatom-Doped Carbon Nanomaterials as Highly Efficient Catalysts for Fuel Cells and Metal-Air Batteries.杂原子掺杂碳纳米材料作为高效燃料电池和金属-空气电池催化剂的设计原则。
Adv Mater. 2015 Nov 18;27(43):6834-40. doi: 10.1002/adma.201503211. Epub 2015 Sep 29.
3
Promoting effect of Co in Ni(m)Co(n) (m + n = 4) bimetallic electrocatalysts for methanol oxidation reaction.
A comparative study of α-Ni(OH) and Ni nanoparticle supported ZIF-8@reduced graphene oxide-derived nitrogen doped carbon for electrocatalytic ethanol oxidation.
α-Ni(OH)与负载镍纳米颗粒的ZIF-8@还原氧化石墨烯衍生氮掺杂碳用于电催化乙醇氧化的比较研究。
RSC Adv. 2024 Feb 13;14(8):5524-5541. doi: 10.1039/d3ra08208c. eCollection 2024 Feb 7.
4
Molten Salts Approach of Poly(vinyl alcohol)-Derived Bimetallic Nickel-Iron Sheets Supported on Porous Carbon Nanosheet as an Effective and Durable Electrocatalyst for Methanol Oxidation.以多孔碳纳米片为载体的聚（乙烯醇）衍生双金属镍铁薄片的熔盐法制备及其作为甲醇氧化有效且耐用的电催化剂
Gels. 2023 Mar 17;9(3):238. doi: 10.3390/gels9030238.
5
Applications of Ceramic/Graphene Composites and Hybrids.陶瓷/石墨烯复合材料及混合材料的应用
Materials (Basel). 2021 Apr 20;14(8):2071. doi: 10.3390/ma14082071.
6
Effect of Anode Material on Electrochemical Oxidation of Low Molecular Weight Alcohols-A Review.阳极材料对低分子量醇类电化学氧化的影响——综述
Molecules. 2021 Apr 9;26(8):2144. doi: 10.3390/molecules26082144.
钴在Ni(m)Co(n)（m + n = 4）双金属电催化剂中对甲醇氧化反应的促进作用。
ACS Appl Mater Interfaces. 2015 Jan 14;7(1):493-503. doi: 10.1021/am506554b. Epub 2014 Dec 17.
4
Reduced graphene oxide (RGO)-supported NiCo₂O₄ nanoparticles: an electrocatalyst for methanol oxidation.还原氧化石墨烯（RGO）负载的NiCo₂O₄纳米颗粒：一种用于甲醇氧化的电催化剂。
Nanoscale. 2014 Sep 21;6(18):10657-65. doi: 10.1039/c4nr02370f. Epub 2014 Aug 4.
5
Nickel oxide hollow microsphere for non-enzyme glucose detection.用于非酶葡萄糖检测的氧化镍空心微球。
Biosens Bioelectron. 2014 Apr 15;54:251-7. doi: 10.1016/j.bios.2013.11.006. Epub 2013 Nov 12.
6
Evidence of ammonium ion-exchange properties of natural bentonite and application to ammonium detection.天然膨润土的铵离子交换性能及其在铵检测中的应用。
Mater Sci Eng C Mater Biol Appl. 2013 Dec 1;33(8):5084-9. doi: 10.1016/j.msec.2013.09.005. Epub 2013 Sep 15.
7
Highly improved electrooxidation of glucose at a nickel(II) oxide/multi-walled carbon nanotube modified glassy carbon electrode.镍(II)氧化物/多壁碳纳米管修饰玻碳电极对葡萄糖的电氧化具有显著增强作用。
Bioelectrochemistry. 2010 Feb;77(2):120-4. doi: 10.1016/j.bioelechem.2009.07.007. Epub 2009 Jul 21.
8
Fabrication of Graphene/Polyaniline Composite Paper via In Situ Anodic Electropolymerization for High-Performance Flexible Electrode.通过原位阳极电聚合制备用于高性能柔性电极的石墨烯/聚苯胺复合纸。
ACS Nano. 2009 Jul 28;3(7):1745-52. doi: 10.1021/nn900297m. Epub 2009 Jun 2.
9
A class of non-precious metal composite catalysts for fuel cells.一类用于燃料电池的非贵金属复合催化剂。
Nature. 2006 Sep 7;443(7107):63-6. doi: 10.1038/nature05118.