• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

由吡啶酰胺锌（II）催化剂制备的左旋、右旋和消旋丙交酯与ε-己内酯的定制嵌段共聚物——一锅法顺序开环聚合反应

Tailor-made block copolymers of l-, d- and -lactides and ε-caprolactone one-pot sequential ring opening polymerization by pyridylamidozinc(ii) catalysts.

作者信息

D'Auria Ilaria, D'Alterio Massimo Christian, Tedesco Consiglia, Pellecchia Claudio

机构信息

Dipartimento di Chimica e Biologia "A. Zambelli", Università Degli Studi di Salerno Via Giovanni Paolo II 132 84084 Fisciano SA Italy

Dipartimento di Scienze Chimiche, Università "Federico II" di Napoli Via Cintia 21 80126 Napoli Italy.

出版信息

RSC Adv. 2019 Oct 14;9(56):32771-32779. doi: 10.1039/c9ra07133d. eCollection 2019 Oct 10.

DOI:10.1039/c9ra07133d
PMID:35529720
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9073191/
Abstract

Three-coordinated Zn(ii) complexes bearing sterically encumbered bidentate monoanionic [, ] pyridylamido ligands efficiently catalyze the ring opening polymerization of lactide (LA) and ε-caprolactone (CL). Owing to the polymerization controlled nature and high rate, precise stereodiblock poly(LLA--DLA) with different block lengths can be easily produced by one-pot sequential monomer addition at room temperature in short reaction times. NMR, SEC and DSC analyses confirm the production of highly isotactic diblock copolymers which crystallize in the high melting stereocomplex phase. Stereo-triblock and tetrablock copolymers of l-LA, d-LA and -LA have been synthesized similarly. Finally, a diblock poly(CL--LA) has been easily obtained by sequential addition of ε-caprolactone and lactide under mild conditions.

摘要

带有空间位阻双齿单阴离子[, ]吡啶酰胺配体的三配位锌（II）配合物能够高效催化丙交酯（LA）和ε-己内酯（CL）的开环聚合反应。由于聚合反应具有可控性且速率较高，通过在室温下短反应时间内一锅法顺序添加单体，能够轻松制备出具有不同嵌段长度的精确立体双嵌段聚（LLA--DLA）。核磁共振（NMR）、尺寸排阻色谱（SEC）和差示扫描量热法（DSC）分析证实生成了在高熔点立体复合相结晶的高度全同立构双嵌段共聚物。l-LA、d-LA和-LA的立体三嵌段和四嵌段共聚物也已通过类似方法合成。最后，在温和条件下通过顺序添加ε-己内酯和丙交酯，轻松获得了双嵌段聚（CL--LA）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/def93717dec2/c9ra07133d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/2789b31682cc/c9ra07133d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/ca80e8a1e84d/c9ra07133d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/4d44857cca03/c9ra07133d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/d15568f3781f/c9ra07133d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/d2f70d438753/c9ra07133d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/2bbe5191737d/c9ra07133d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/def93717dec2/c9ra07133d-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/2789b31682cc/c9ra07133d-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/ca80e8a1e84d/c9ra07133d-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/4d44857cca03/c9ra07133d-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/d15568f3781f/c9ra07133d-s2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/d2f70d438753/c9ra07133d-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/2bbe5191737d/c9ra07133d-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/048d/9073191/def93717dec2/c9ra07133d-f5.jpg

相似文献

1
Tailor-made block copolymers of l-, d- and -lactides and ε-caprolactone one-pot sequential ring opening polymerization by pyridylamidozinc(ii) catalysts.由吡啶酰胺锌（II）催化剂制备的左旋、右旋和消旋丙交酯与ε-己内酯的定制嵌段共聚物——一锅法顺序开环聚合反应
RSC Adv. 2019 Oct 14;9(56):32771-32779. doi: 10.1039/c9ra07133d. eCollection 2019 Oct 10.
2
β-Pyridylenolate zinc catalysts for the ring-opening homo- and copolymerization of ε-caprolactone and lactides.β-吡啶醇盐锌催化剂用于ε-己内酯和丙交酯的开环均聚和共聚。
Dalton Trans. 2017 Aug 14;46(30):9846-9858. doi: 10.1039/c7dt01877k. Epub 2017 Jul 7.
3
Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes.水杨醛缩邻氨基酚铝配合物催化丙交酯和ε-己内酯的开环均聚和共聚反应
Dalton Trans. 2015 Feb 7;44(5):2157-65. doi: 10.1039/c4dt02616k.
4
Highly Active Homoleptic Zinc and Magnesium Complexes Supported by Constrained Reduced Schiff Base Ligands for the Ring-Opening Polymerization of Lactide.受受限缩希夫碱配体稳定的高活性均相锌和镁配合物用于丙交酯的开环聚合。
Inorg Chem. 2021 Nov 15;60(22):17114-17122. doi: 10.1021/acs.inorgchem.1c02382. Epub 2021 Oct 4.
5
Synthesis and Characterization of Double Crystalline Cyclic Diblock Copolymers of Poly(ε-caprolactone) and Poly(l(d)-lactide) (c(PCL-b- PL(D)LA)).聚（ε-己内酯）和聚（l（d）-丙交酯）（c（PCL-b-PL（D）LA））双晶环状二嵌段共聚物的合成与表征
Macromol Rapid Commun. 2016 Oct;37(20):1676-1681. doi: 10.1002/marc.201600309. Epub 2016 Aug 29.
6
Syntheses, characterization, and in vitro degradation of ethyl cellulose-graft-poly(epsilon-caprolactone)-block-poly(L-lactide) copolymers by sequential ring-opening polymerization.通过顺序开环聚合合成、表征及体外降解乙基纤维素接枝聚（ε-己内酯）-嵌段聚（L-丙交酯）共聚物
Biomacromolecules. 2007 Apr;8(4):1101-8. doi: 10.1021/bm0610018. Epub 2007 Feb 28.
7
Mechanistic Insight into the Ring-Opening Polymerization of -Caprolactone and -Lactide Using Ketiminate-Ligated Aluminum Catalysts.关于使用酮亚胺配位铝催化剂对己内酯和丙交酯进行开环聚合反应的机理洞察。
Polymers (Basel). 2019 Sep 19;11(9):1530. doi: 10.3390/polym11091530.
8
Tailor-Made Stereoblock Copolymers of Poly(lactic acid) by a Truly Living Polymerization Catalyst.采用真正的活性聚合催化剂制备聚乳酸的定制立体嵌段共聚物。
J Am Chem Soc. 2016 Sep 21;138(37):12041-4. doi: 10.1021/jacs.6b07287. Epub 2016 Sep 12.
9
Toughening Poly(l-lactide) Blends: Effectiveness of Sequence-Controlled Six-Arm Star-Branched Block Copolymers of Poly(l-lactide) and Poly(ε-caprolactone).聚（L-丙交酯）共混物的增韧：聚（L-丙交酯）与聚（ε-己内酯）的序列控制六臂星形嵌段共聚物的有效性
ACS Omega. 2022 Mar 9;7(11):9118-9129. doi: 10.1021/acsomega.1c04486. eCollection 2022 Mar 22.
10
Synthesis, structure and properties of poly(L-lactide-co-ε-caprolactone) statistical copolymers.聚（L-丙交酯-共-ε-己内酯）统计共聚物的合成、结构和性能。
J Mech Behav Biomed Mater. 2012 May;9:100-12. doi: 10.1016/j.jmbbm.2012.01.003. Epub 2012 Jan 18.

引用本文的文献

1
Ring Opening Polymerization of Six- and Eight-Membered Racemic Cyclic Esters for Biodegradable Materials.开环聚合的六和八成员的外消旋环状酯的可生物降解材料。
Int J Mol Sci. 2024 Jan 29;25(3):1647. doi: 10.3390/ijms25031647.
2
Polylactide Perspectives in Biomedicine: From Novel Synthesis to the Application Performance.生物医学中的聚乳酸研究进展：从新型合成到应用性能
Pharmaceutics. 2022 Aug 11;14(8):1673. doi: 10.3390/pharmaceutics14081673.
3
Crystallization, thermal and mechanical properties of stereocomplexed poly(lactide) with flexible PLLA/PCL multiblock copolymer.

本文引用的文献

1
Occurrence, sources, human health impacts and mitigation of microplastic pollution.微塑料污染的发生、来源、对人类健康的影响及缓解措施。
Environ Sci Pollut Res Int. 2018 Dec;25(36):36046-36063. doi: 10.1007/s11356-018-3508-7. Epub 2018 Oct 31.
2
Block-Stereoblock Copolymers of Poly(ϵ-Caprolactone) and Poly(Lactic Acid).聚（ε-己内酯）与聚乳酸的嵌段-立构嵌段共聚物
Angew Chem Int Ed Engl. 2018 Jun 11;57(24):7191-7195. doi: 10.1002/anie.201803063. Epub 2018 May 14.
3
Catalysis as an Enabling Science for Sustainable Polymers.催化科学在可持续聚合物中的应用
具有柔性聚乳酸/聚己内酯多嵌段共聚物的立体复合聚乳酸的结晶、热性能和力学性能
RSC Adv. 2022 May 3;12(21):13180-13191. doi: 10.1039/d2ra00461e. eCollection 2022 Apr 28.
4
Synthesis of High Molecular Weight Stereo-Di-Block Copolymers Driven by a Co-Initiator Free Catalyst.由无共引发剂催化剂驱动合成高分子量立构双嵌段共聚物
Polymers (Basel). 2022 Jan 7;14(2):232. doi: 10.3390/polym14020232.
5
Thermo-Rheological and Shape Memory Properties of Block and Random Copolymers of Lactide and ε-Caprolactone.丙交酯与ε-己内酯的嵌段共聚物和无规共聚物的热流变学及形状记忆性能
Polymers (Basel). 2021 Feb 19;13(4):627. doi: 10.3390/polym13040627.
Chem Rev. 2018 Jan 24;118(2):839-885. doi: 10.1021/acs.chemrev.7b00329. Epub 2017 Oct 19.
4
Divergent [{ONNN}Mg-Cl] complexes in highly active and living lactide polymerization.高活性及活性丙交酯聚合反应中的发散型[{ONNN}Mg-Cl]配合物
Chem Sci. 2017 Aug 1;8(8):5476-5481. doi: 10.1039/c7sc01514c. Epub 2017 May 26.
5
New homoleptic bis(pyrrolylpyridiylimino) Mg(ii) and Zn(ii) complexes as catalysts for the ring opening polymerization of cyclic esters via an "activated monomer" mechanism.新型均配双（吡咯基吡啶基亚氨基）镁（II）和锌（II）配合物作为通过“活化单体”机理催化环酯开环聚合的催化剂。
Dalton Trans. 2017 Sep 28;46(36):12217-12225. doi: 10.1039/c7dt02445b. Epub 2017 Sep 6.
6
Tailor-Made Stereoblock Copolymers of Poly(lactic acid) by a Truly Living Polymerization Catalyst.采用真正的活性聚合催化剂制备聚乳酸的定制立体嵌段共聚物。
J Am Chem Soc. 2016 Sep 21;138(37):12041-4. doi: 10.1021/jacs.6b07287. Epub 2016 Sep 12.
7
Zinc Complexes of Sequential Tetradentate Monoanionic Ligands in the Isoselective Polymerization of rac-Lactide.外消旋丙交酯等规选择性聚合中顺序四齿单阴离子配体的锌配合物
Chemistry. 2016 Aug 8;22(33):11533-6. doi: 10.1002/chem.201601979. Epub 2016 Jul 4.
8
Poly(lactic acid)-Mass production, processing, industrial applications, and end of life.聚乳酸-大规模生产、加工、工业应用和生命周期终结。
Adv Drug Deliv Rev. 2016 Dec 15;107:333-366. doi: 10.1016/j.addr.2016.03.010. Epub 2016 Apr 1.
9
P,O-Phosphinophenolate zinc(II) species: synthesis, structure and use in the ring-opening polymerization (ROP) of lactide, ε-caprolactone and trimethylene carbonate.磷酰基酚锌（II）物种：合成、结构及其在丙交酯、ε-己内酯和碳酸三亚甲酯的开环聚合（ROP）中的应用
Dalton Trans. 2015 Jul 21;44(27):12376-87. doi: 10.1039/c5dt00458f.
10
Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes.水杨醛缩邻氨基酚铝配合物催化丙交酯和ε-己内酯的开环均聚和共聚反应
Dalton Trans. 2015 Feb 7;44(5):2157-65. doi: 10.1039/c4dt02616k.