Raifuku Itaru, Ishikawa Yasuaki, Chiang Yu-Hsien, Lin Pei-Ying, Li Ming-Hsien, Uraoka Yukiharu, Chen Peter
Division of Materials Science, Nara Institute of Science and Technology 8916-5 Takayama Ikoma Nara 630-0192 Japan
Department of Photonics and Hierarchical Green-Energy Materials (Hi-GEM) Research Center, National Cheng Kung University No.1, University Rd. Tainan 701 Taiwan.
RSC Adv. 2019 Oct 15;9(56):32833-32838. doi: 10.1039/c9ra05323a. eCollection 2019 Oct 10.
Perovskite solar cells have attracted much attention as next-generation solar cells because of their high efficiency and low fabrication costs. Moreover, perovskite solar cells are a promising candidate for indoor energy harvesting. We investigated the effect of bandgap tuning on the characteristics of triple cation-based perovskite solar cells under fluorescent lamp illumination. According to the current density-voltage curves, perovskite solar cells with a wider bandgap than the conventional one exhibited improved open-circuit voltage without sacrificing short-circuit current density under fluorescent lamp illumination. Moreover, the wider bandgap perovskite films including a large amount of bromine in the composition did not show phase segregation, which can degrade the photovoltaic performance of perovskite solar cells, after fluorescent lamp illumination. Our results demonstrate the facile strategy to improve the performance of perovskite solar cells under ambient lighting and great potential of perovskite solar cells for indoor applications such as power sources for the internet of things.
钙钛矿太阳能电池因其高效率和低制造成本而作为下一代太阳能电池备受关注。此外,钙钛矿太阳能电池是室内能量收集的一个有前途的候选者。我们研究了在荧光灯照明下带隙调谐对基于三阳离子的钙钛矿太阳能电池特性的影响。根据电流密度-电压曲线,与传统钙钛矿太阳能电池相比,具有更宽带隙的钙钛矿太阳能电池在荧光灯照明下表现出开路电压的提高,而不牺牲短路电流密度。此外,在组成中包含大量溴的更宽带隙钙钛矿薄膜在荧光灯照明后未表现出会降低钙钛矿太阳能电池光伏性能的相分离。我们的结果证明了在环境光下提高钙钛矿太阳能电池性能的简便策略以及钙钛矿太阳能电池在诸如物联网电源等室内应用中的巨大潜力。