Wang Cong, Hill Malik, Theard Brandon, Mack James
Department of Chemistry, University of Cincinnati 404 Crosley Tower Cincinnati Ohio USA
RSC Adv. 2019 Sep 4;9(48):27888-27891. doi: 10.1039/c9ra04921e. eCollection 2019 Sep 3.
Polyaromatic hydrocarbons are central molecules in the future of nanotechnology. However, the synthesis of these molecules is limited by their lack of solubility in solvents, especially green solvents, their ease of oxidation in solution and use of harmful reagents. Solvent-free mechanochemistry has been shown to have excellent potential for these types of molecules and should provide a much more environmentally benign approach for the synthesis of this very important class of molecules. This report details the use of mechanochemistry on an iterative strategy for the synthesis of polyaromatic hydrocarbon derivatives.
多环芳烃是纳米技术未来的核心分子。然而，这些分子的合成受到其在溶剂（尤其是绿色溶剂）中缺乏溶解性、在溶液中易于氧化以及使用有害试剂的限制。无溶剂机械化学已被证明对这类分子具有巨大潜力，并且应该为合成这一非常重要的分子类别提供一种对环境更友好的方法。本报告详细介绍了机械化学在多环芳烃衍生物合成的迭代策略中的应用。
