Friščić Tomislav, Mottillo Cristina, Titi Hatem M
Department of Chemistry, McGill University, 801 Sherbrooke St. W., H3A 0B8, Montreal, Canada.
Laboratoire SPCMIB, CNRS UMR 5068, Université de Toulouse UPS, 118 Route de Narbonne, 31062, Toulouse Cedex 09, France.
Angew Chem Int Ed Engl. 2020 Jan 13;59(3):1018-1029. doi: 10.1002/anie.201906755. Epub 2019 Sep 24.
Mechanochemical solvent-free reactions by milling, grinding or other types of mechanical action have emerged as a viable alternative to solution chemistry. Mechanochemistry offers not only a possibility to eliminate the need for bulk solvent use, and reduce the generation of waste, but it also unlocks the door to a different reaction environment in which synthetic strategies, reactions and molecules previously not accessible in solution, can be achieved. This Minireview examines the potential of mechanochemistry in chemical and materials synthesis, by providing a cross-section of the recent developments in using ball milling for the formation of molecules and materials based on covalent and coordination bonds.
通过研磨、粉碎或其他类型的机械作用进行的机械化学无溶剂反应已成为溶液化学的一种可行替代方法。机械化学不仅提供了消除大量使用溶剂的需求并减少废物产生的可能性，而且还开启了通向不同反应环境的大门，在这种环境中，可以实现以前在溶液中无法获得的合成策略、反应和分子。本综述通过提供使用球磨形成基于共价键和配位键的分子和材料的最新进展的横断面，探讨了机械化学在化学和材料合成中的潜力。
