叔丁醇钾引发的成键反应。
BuOK-triggered bond formation reactions.
作者信息
Xu Yulong, Shi Xiaonan, Wu Lipeng
机构信息
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Suzhou Research Institute of LICP, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences Lanzhou 730000 P. R. China
出版信息
RSC Adv. 2019 Aug 2;9(41):24025-24029. doi: 10.1039/c9ra04242c. eCollection 2019 Jul 29.
Recently, inexpensive and readily available BuOK has seen widespread use in transition-metal-free reactions. Herein, we report the use of BuOK for S-S, S-Se, N[double bond, length as m-dash]N and C[double bond, length as m-dash]N bond formations, which significantly extends the scope of BuOK in chemical synthesis. Compared with traditional methods, we have realized mild and general methods for disulfide, azobenzenes imine synthesis.
最近，价格低廉且易于获得的叔丁醇钾已在无过渡金属反应中得到广泛应用。在此，我们报道了叔丁醇钾在S-S、S-Se、N=N和C=N键形成反应中的应用，这显著扩展了叔丁醇钾在化学合成中的应用范围。与传统方法相比，我们实现了温和且通用的二硫化物、偶氮苯亚胺合成方法。
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