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添加碳化硅纳米颗粒提高Al-17Si-3.5Cu的热导率和拉伸强度。

Enhanced thermal conductivity and tensile strength of Al-17Si-3.5Cu with SiC-nanoparticle addition.

作者信息

Jiang D P, Yu J K

机构信息

State Key Laboratory of Solidification Processing, Northwestern Polytechnical University Xi'an 710072 P.R. China

出版信息

RSC Adv. 2019 Oct 28;9(60):34677-34690. doi: 10.1039/c9ra07253e.

Abstract

The morphology and size of primary Si has a significant influence on the thermal conductivity (TC) and strength of Al-17Si-3.5Cu. In this study, the effect of a 1-3 wt% SiC nanoparticle (SiC) addition on TC and tensile strength of Al-17Si-3.5Cu was investigated. Nanoparticles distributed at the interface between primary Si and Al led to a significant refinement of primary Si; for example, a primary Si size of 2 μm with 3 wt% SiC addition was achieved. TC of SiC/Al-17Si-3.5Cu improved with an increase in nanoparticle content. Nanoparticles distributed at the interface between Si and Al reduced the interfacial thermal resistance. Thus, the effective TC of eutectic Si increased. Owing to the refinement of the primary Si and the increased interfacial thermal resistance, originating from the high content of SiC at the interface, the effective TC of primary Si decreased. Compared with Al-17Si-3.5Cu, contribution to the improvement of the TC of SiC/Al-17Si-3.5Cu resulted mainly from eutectic Si. Due to the refinement of primary Si, the tensile strength of SiC/Al-17Si-3.5Cu improved with an increase in SiC content. When the SiC content was 3 wt%, the yield strength, ultimate tensile strength and elongation of SiC/Al-17Si-3.5Cu were ∼176 MPa, 418 MPa and 7%, respectively, which were improved by 37.5%, 53.7% and 218%, respectively, when compared with Al-17Si-3.5Cu.

摘要

初生硅的形态和尺寸对Al-17Si-3.5Cu的热导率(TC)和强度有显著影响。在本研究中,研究了添加1-3 wt%的碳化硅纳米颗粒(SiC)对Al-17Si-3.5Cu的热导率和拉伸强度的影响。分布在初生硅和铝界面处的纳米颗粒导致初生硅显著细化;例如,添加3 wt% SiC时可实现2μm的初生硅尺寸。SiC/Al-17Si-3.5Cu的热导率随纳米颗粒含量的增加而提高。分布在硅和铝界面处的纳米颗粒降低了界面热阻。因此,共晶硅的有效热导率增加。由于初生硅的细化以及界面处SiC含量高导致界面热阻增加,初生硅的有效热导率降低。与Al-17Si-3.5Cu相比,SiC/Al-17Si-3.5Cu热导率提高的贡献主要来自共晶硅。由于初生硅的细化,SiC/Al-17Si-3.5Cu的拉伸强度随SiC含量的增加而提高。当SiC含量为3 wt%时,SiC/Al-17Si-3.5Cu的屈服强度、极限抗拉强度和伸长率分别约为176 MPa、418 MPa和7%,与Al-17Si-3.5Cu相比,分别提高了37.5%、53.7%和218%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7283/9074422/c7253fdede2f/c9ra07253e-f1.jpg

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