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一种用于光催化降解废水中四环素的新型碳纳米管-铁镍/双功能纳米硅球/铜(II)磁性纳米复合材料的合成与表征

Synthesis and characterization of a novel CNT-FeNi/DFNS/Cu(ii) magnetic nanocomposite for the photocatalytic degradation of tetracycline in wastewater.

作者信息

Zhao Yanhua, Tang Jie Juan, Motavalizadehkakhky Alireza, Kakooei Saeid, Sadeghzadeh Seyed Mohsen

机构信息

School of Economics and Management, Langfang Normal University Langfang 065000 China.

Department of Public Health and Preventive Medicine, Changzhi Medical College 046000 China.

出版信息

RSC Adv. 2019 Oct 30;9(60):35022-35032. doi: 10.1039/c9ra05817f. eCollection 2019 Oct 28.

Abstract

Herein, Cu(ii) complexes were anchored within the nanospaces of a magnetic fibrous silicate with a high surface area and easily accessible active sites a facile approach, leading to the successful synthesis of a novel potent nanocatalyst (FeNi/DFNS/Cu). Furthermore, FeNi/DFNS/Cu was supported on carbon nanotubes (CNTs) an usual nozzle electrospinning method (CNT-FeNi/DFNS/Cu). In addition, its performance as a photocatalyst for the degradation of tetracycline was tested in a batch reactor. Tetracycline is an antibiotic that is commonly utilized in veterinary medicine and in the treatment of human infections, but is hazardous to aquatic environments. However, the usual processes for the removal of tetracycline are not efficient. The eco-friendly attributes of this catalytic system include high catalytic activity and ease of recovery from the reaction mixture using an external magnet, and it can be reused several times without significant loss in its performance. Also, protocols such as hot filtration, and mercury poisoning provided complete insight into the nature of this heterogeneous catalyst.

摘要

在此,通过一种简便的方法将铜(II)配合物锚定在具有高表面积和易于接近的活性位点的磁性纤维状硅酸盐的纳米空间内,成功合成了一种新型高效纳米催化剂(FeNi/DFNS/Cu)。此外,通过常规的喷嘴电纺丝方法将FeNi/DFNS/Cu负载在碳纳米管上(CNT-FeNi/DFNS/Cu)。此外,在间歇式反应器中测试了其作为光催化剂降解四环素的性能。四环素是一种常用于兽医学和治疗人类感染的抗生素,但对水生环境有害。然而,去除四环素的常规方法效率不高。该催化体系的环保特性包括高催化活性以及使用外部磁铁易于从反应混合物中回收,并且可以重复使用多次而其性能无显著损失。此外,热过滤和汞中毒等实验方案全面深入地揭示了这种多相催化剂的性质。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b244/9074154/faf9204714b3/c9ra05817f-s1.jpg

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