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将污水污泥与煤混合对燃烧和灰渣结渣行为的影响。

Effect of blending sewage sludge with coal on combustion and ash slagging behavior.

作者信息

Guo Shuai, Yang Qiyao, Liang Honglin, Che Deyong, Liu Hongpeng, Sun Baizhong

机构信息

School of Energy and Power Engineering, Northeast Electric Power University Jilin 132000 China

出版信息

RSC Adv. 2019 Sep 19;9(51):29482-29492. doi: 10.1039/c9ra04243a. eCollection 2019 Sep 18.

Abstract

Blending sewage sludge (SS) with Zhundong coal (ZDC) for combustion in coal-fired power plants is a recent approach that can alleviate the shortage of high-quality coal resources and achieve the harmless treatment of SS, while also having a significant influence on combustion and ash slagging. Due to the high content of alkali and alkaline earth metals (AAEMs) in ZDC, its combustion ash has a strong likelihood of slagging. This study aims to investigate the effect of blending SS with ZDC on combustion and ash slagging. Thermogravimetry (TG) results indicate that blending with SS could lower the ignition and burnout temperatures of ZDC. With an increase in the ratio of sludge, the comprehensive combustion index () first increases and then decreases, showing that blending SS with ZDC in an appropriate proportion could improve the overall combustion. Through the analysis of the interaction, it is confirmed that SS and ZDC could complement each other during co-combustion due to their different components. X-ray fluorescence (XRF) was used to test the ash components of different blending ratios (10-30%) and combustion temperatures (800-1100 °C). Slagging indices including alkali acid ratio (/), silicon ratio (), and silica-alumina ratio (SiO/AlO) were also calculated. The results suggest that the slagging behavior of ZDC is greatly reduced even if the blending ratio is only 10%. However, with an increase in the blending ratio, the effect on slagging gradually weakens. Considering the dual influence of SS blending on combustion and slagging, this study assumes the optimal blending ratio of 20%. Influenced by the components of the combustion ash, / and SiO/AlO are more suitable for evaluating the slagging tendency of ash; however, there is great deviation in the results for . This research is beneficial to coal-fired power plants for the selection of operation parameters during co-combustion with SS.

摘要

将污水污泥(SS)与准东煤(ZDC)混合用于燃煤电厂燃烧是一种新方法,它可以缓解优质煤炭资源短缺问题,并实现污水污泥的无害化处理,同时对燃烧和灰渣结渣也有重大影响。由于准东煤中碱金属和碱土金属(AAEMs)含量高,其燃烧灰分很有可能结渣。本研究旨在探究将污水污泥与准东煤混合对燃烧和灰渣结渣的影响。热重分析(TG)结果表明,与污水污泥混合可降低准东煤的着火和燃尽温度。随着污泥比例增加,综合燃烧指数()先增大后减小,表明以适当比例将污水污泥与准东煤混合可改善整体燃烧情况。通过相互作用分析,证实由于污水污泥和准东煤成分不同,它们在共燃烧过程中可相互补充。采用X射线荧光光谱法(XRF)测试了不同混合比例(10%-30%)和燃烧温度(800-1100℃)下的灰分成分。还计算了包括碱酸比(/)、硅比()和硅铝比(SiO/AlO)在内的结渣指数。结果表明,即使混合比例仅为10%,准东煤的结渣行为也会大大降低。然而,随着混合比例增加,对结渣的影响逐渐减弱。考虑到污水污泥混合对燃烧和结渣的双重影响,本研究假设最佳混合比例为20%。受燃烧灰分成分影响,/和SiO/AlO更适合评估灰分的结渣倾向;然而,对于的结果存在很大偏差。本研究有助于燃煤电厂在与污水污泥共燃烧过程中选择运行参数。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/672d/9071929/ff313042b014/c9ra04243a-f1.jpg

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