Element-Doped Mxenes: Mechanism, Synthesis, and Applications.

Heteroatom doping can endow MXenes with various new or improved electromagnetic, physicochemical, optical, and structural properties. This greatly extends the arsenal of MXenes materials and their potential for a spectrum of applications. This article comprehensively and critically discusses the syntheses, properties, and emerging applications of the growing family of heteroatom-doped MXenes materials. First, the doping strategies, synthesis methods, and theoretical simulations of high-performance MXenes materials are summarized. In order to achieve high-performance MXenes materials, the mechanism of atomic element doping from three aspects of lattice optimization, functional substitution, and interface modification is analyzed and summarized, aiming to provide clues for developing new and controllable synthetic routes. The mechanisms underlying their advantageous uses for energy storage, catalysis, sensors, environmental purification and biomedicine are highlighted. Finally, future opportunities and challenges for the study and application of multifunctional high-performance MXenes are presented. This work could open up new prospects for the development of high-performance MXenes.