Duan Liangfei, Zhang Yumin, Zhao Jianhong, Zhang Jin, Li Qian, Chen Yu, Liu Jing, Liu Qingju
Yunnan Key Laboratory for Micro/Nano Materials & Technology, International Joint Research Center for Optoelectronic and Energy Materials, School of Materials and Energy, Yunnan University, Kunming 650091, People's Republic of China.
CAS Key Laboratory of Cryogenics and Beijing Key Laboratory of Cryo- Biomedical Engineering, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
ACS Appl Mater Interfaces. 2022 May 25;14(20):23951-23963. doi: 10.1021/acsami.2c02714. Epub 2022 May 10.
A liquid metal (LM) generally has excellent electrical conductivity, thermal conductivity, flexibility, fluidity, and reflectivity. Innovative electronics using a LM to paint colorful fluorescent patterns may be applied to many important fields. Herein we propose, for the first time, the use of a LM to paint fluorescent patterns in the field of natural science. An LM containing a main-group metal (GaBiInSn) is used to paint a uniform alloy film on a ceramic substrate. The painting is not restricted by any curved surface, shape, or size, which therefore gives the LM diverse adaptability. We have adopted the strategy of "painting-annealing-dealloying" through which LM can easily be diffused and doped into the substrate to produce various defects. Defects, my themselves or through their interactions, can produce different colors of emitted light. The primary fluorescence colors, such as purple, yellow, blue, and white, have been painted with the LM. Importantly, the brightness and color coordinates can be adjusted by changing the LM composition or annealing temperature, and intricate, delicate, colorful fluorescence patterns can be produced. Due to the unique painting form, colorful fluorescence, high stability, corrosion resistance, and low cost of the technique used for the LM, it can be used for displays, lighting panels, flexible electronic circuits, anticounterfeiting devices, and sensors.
液态金属(LM)通常具有优异的导电性、导热性、柔韧性、流动性和反射率。使用液态金属绘制彩色荧光图案的创新电子产品可应用于许多重要领域。在此,我们首次提出在自然科学领域使用液态金属绘制荧光图案。一种含有主族金属(镓铋铟锡)的液态金属被用于在陶瓷基板上绘制均匀的合金膜。这种绘制不受任何曲面、形状或尺寸的限制,因此赋予了液态金属多种适应性。我们采用了“绘制-退火-脱合金”策略,通过该策略,液态金属可以轻松扩散并掺杂到基板中以产生各种缺陷。缺陷本身或通过它们之间的相互作用,可以产生不同颜色的发射光。已经用液态金属绘制出了紫色、黄色、蓝色和白色等主要荧光颜色。重要的是,通过改变液态金属的成分或退火温度,可以调整亮度和颜色坐标,并能产生复杂、精致、色彩丰富的荧光图案。由于液态金属独特的绘制形式、彩色荧光、高稳定性、耐腐蚀性以及所使用技术的低成本,它可用于显示器、照明面板、柔性电子电路、防伪装置和传感器。