Otitoju Tunmise Ayode, Ahmad Abdul Latif, Ooi Boon Seng
School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia 14300 Nibong Tebal Penang Malaysia
RSC Adv. 2018 Jun 20;8(40):22710-22728. doi: 10.1039/c8ra03296c. eCollection 2018 Jun 19.
The blending of additives in the polyethersulfone (PES) matrix is an important approach in the membrane industry to reduce membrane hydrophobicity and improve the performance (flux, solute rejection, and reduction of fouling). Several (hydrophilic) modifications of the PES membrane have been developed. Given the importance of the hydrophilic modification methods for PES membranes and their applications, we decided to dedicate this review solely to this topic. The types of additives embedded into the PES matrix can be divided into two main categories: (i) polymers and (ii) inorganic nanoparticles (NPs). The introduced polymers include polyvinylpyrrolidone, chitosan, polyamide, polyethylene oxide, and polyethylene glycol. The introduced nanoparticles discussed include titanium, iron, aluminum, silver, zirconium, silica, magnesium based NPs, carbon, and halloysite nanotubes. In addition, the applications of hydrophilic PES membranes are also reviewed. Reviewing the research progress in the hydrophilic modification of PES membranes is necessary and imperative to provide more insights for their future development and perhaps to open the door to extend their applications to other more challenging areas.
在聚醚砜(PES)基质中添加添加剂是膜工业中降低膜疏水性并改善性能(通量、溶质截留率和减少污染)的重要方法。已经开发了几种对PES膜的(亲水性)改性方法。鉴于PES膜亲水性改性方法及其应用的重要性,我们决定将本综述专门针对这一主题。嵌入PES基质中的添加剂类型可分为两大类:(i)聚合物和(ii)无机纳米颗粒(NPs)。引入的聚合物包括聚乙烯吡咯烷酮、壳聚糖、聚酰胺、聚环氧乙烷和聚乙二醇。讨论的引入的纳米颗粒包括钛、铁、铝、银、锆、二氧化硅、镁基纳米颗粒、碳和埃洛石纳米管。此外,还综述了亲水性PES膜的应用。回顾PES膜亲水性改性的研究进展对于为其未来发展提供更多见解并可能为将其应用扩展到其他更具挑战性的领域打开大门是必要且势在必行的。