• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双苯基乙炔基多面体低聚倍半硅氧烷：新型高温可加工热固性材料。

Bis-phenylethynyl polyhedral oligomeric silsesquioxanes: new high-temperature, processable thermosetting materials.

作者信息

Moore Levi M J, Zavala Jacob J, Lamb Jason T, Reams Josiah T, Yandek Gregory R, Guenthner Andrew J, Haddad Timothy S, Ghiassi Kamran B

机构信息

Air Force Research Laboratory, Aerospace Systems Directorate, Edwards AFB California 93524 USA

ERC Incorporated, Edwards AFB California 93524 USA.

出版信息

RSC Adv. 2018 Jul 31;8(48):27400-27405. doi: 10.1039/c8ra05954c. eCollection 2018 Jul 30.

DOI:10.1039/c8ra05954c
PMID:35539971
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9083338/
Abstract

Bis-phenylethynyl polyhedral oligomeric silsesquioxane (bis-PE-POSS) compounds were synthesized and thermally cured yielding crosslinked materials. After curing at 370 °C, thermal decomposition occurs near 600 °C under nitrogen. These materials were synthesized by condensation of a new phenylethynyl-functional dichlorosilane onto tetrasilanol phenyl POSS, yielding two geometric isomers.

摘要

双苯乙炔基多面体低聚倍半硅氧烷（双-PE-POSS）化合物被合成出来，并通过热固化得到交联材料。在370℃固化后，在氮气氛围下，热分解在600℃左右发生。这些材料是通过一种新型苯乙炔基官能化二氯硅烷与四硅醇苯基POSS缩合而成，产生了两种几何异构体。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/310c05bb6dae/c8ra05954c-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/8d738b83f57d/c8ra05954c-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/24b45c2aaea2/c8ra05954c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/ac1a487aa037/c8ra05954c-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/d47dca82a8cf/c8ra05954c-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/310c05bb6dae/c8ra05954c-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/8d738b83f57d/c8ra05954c-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/24b45c2aaea2/c8ra05954c-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/ac1a487aa037/c8ra05954c-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/d47dca82a8cf/c8ra05954c-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/92f1/9083338/310c05bb6dae/c8ra05954c-f4.jpg

相似文献

1
Bis-phenylethynyl polyhedral oligomeric silsesquioxanes: new high-temperature, processable thermosetting materials.双苯基乙炔基多面体低聚倍半硅氧烷：新型高温可加工热固性材料。
RSC Adv. 2018 Jul 31;8(48):27400-27405. doi: 10.1039/c8ra05954c. eCollection 2018 Jul 30.
2
Reactive Hybrid of Polyhedral Oligomeric Silsesquioxane (POSS) and Sulfur as a Building Block for Self-Healing Materials.作为自愈材料构建单元的多面体低聚倍半硅氧烷（POSS）与硫的反应性杂化物
Macromol Rapid Commun. 2017 May;38(10). doi: 10.1002/marc.201700051. Epub 2017 Mar 30.
3
Multifunctional Properties of Polyhedral Oligomeric Silsesquioxanes (POSS)-Based Epoxy Nanocomposites.基于多面体低聚倍半硅氧烷（POSS）的环氧纳米复合材料的多功能特性
Polymers (Basel). 2023 May 13;15(10):2297. doi: 10.3390/polym15102297.
4
Large Polyhedral Oligomeric Silsesquioxane Cages: The Isolation of Functionalized POSS with an Unprecedented Si O Core.大型多面体低聚倍半硅氧烷笼：具有前所未有的硅-氧核心的功能化倍半硅氧烷的分离
Angew Chem Int Ed Engl. 2021 Feb 8;60(6):3022-3027. doi: 10.1002/anie.202010458. Epub 2020 Dec 3.
5
Fluorinated and Thermo-Cross-Linked Polyhedral Oligomeric Silsesquioxanes: New Organic-Inorganic Hybrid Materials for High-Performance Dielectric Application.氟化和热交联的多面体低聚倍半硅氧烷：用于高性能介电应用的新型有机-无机杂化材料。
ACS Appl Mater Interfaces. 2017 Apr 12;9(14):12782-12790. doi: 10.1021/acsami.7b01415. Epub 2017 Mar 31.
6
Multi-Alkenylsilsesquioxanes as Comonomers and Active Species Modifiers of Metallocene Catalyst in Copolymerization with Ethylene.多链烯基倍半硅氧烷作为茂金属催化剂与乙烯共聚的共聚单体和活性物种调节剂
Polymers (Basel). 2018 Feb 24;10(2):223. doi: 10.3390/polym10020223.
7
Functional polyhedral oligomeric silsesquioxane reinforced poly(lactic acid) nanocomposites for biomedical applications.功能化多面体低聚倍半硅氧烷增强聚乳酸纳米复合材料在生物医学中的应用。
J Mech Behav Biomed Mater. 2019 Feb;90:604-614. doi: 10.1016/j.jmbbm.2018.11.002. Epub 2018 Nov 19.
8
Polyhedral Oligomeric Silsesquioxane D-(RSiO).多面体低聚倍半硅氧烷D-(RSiO)。
Chemistry. 2024 Mar 15;30(16):e202303640. doi: 10.1002/chem.202303640. Epub 2024 Jan 26.
9
Highly efficient phosphorescent materials based on Ir(iii) complexes-grafted on a polyhedral oligomeric silsesquioxane core.基于接枝在多面体低聚倍半硅氧烷核上的铱（III）配合物的高效磷光材料。
Dalton Trans. 2016 Sep 14;45(34):13491-502. doi: 10.1039/c6dt02383e. Epub 2016 Aug 8.
10
Synthesis and Thermal Degradation Study of Polyhedral Oligomeric Silsesquioxane (POSS) Modified Phenolic Resin.多面体低聚倍半硅氧烷（POSS）改性酚醛树脂的合成与热降解研究
Polymers (Basel). 2021 Apr 7;13(8):1182. doi: 10.3390/polym13081182.

引用本文的文献

1
New Ethynylphenylborasilsesquioxanes-Their Reactivity and Behavior during Thermal Decomposition.新型乙撑基苯基硼硅倍半氧烷的热分解反应性及其行为。
Int J Mol Sci. 2023 Sep 11;24(18):13960. doi: 10.3390/ijms241813960.
2
Unprecedented Route to Amide-Functionalized Double-Decker Silsesquioxanes Using Carboxylic Acid Derivatives and a Hydrochloride Salt of Aminopropyl-DDSQ.使用羧酸衍生物和氨基丙基-DDSQ 的盐酸盐，开创酰胺官能化双层笼形倍半硅氧烷的新途径。
Inorg Chem. 2023 Apr 10;62(14):5520-5530. doi: 10.1021/acs.inorgchem.2c04546. Epub 2023 Mar 29.

本文引用的文献

1
Identification and quantification of cis and trans isomers in aminophenyl double-decker silsesquioxanes using 1H-29Si gHMBC NMR.使用 1H-29Si gHMBC NMR 鉴定和定量氨苯基双层硅倍半氧烷中的顺式和反式异构体。
Magn Reson Chem. 2013 Aug;51(8):490-6. doi: 10.1002/mrc.3962. Epub 2013 May 27.
2
Atomic oxygen effects on POSS polyimides in low earth orbit.原子氧对低地球轨道中 POSS 聚酰亚胺的影响。
ACS Appl Mater Interfaces. 2012 Feb;4(2):492-502. doi: 10.1021/am201509n. Epub 2012 Jan 10.