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低频波段活性炭@FeO复合材料的简便合成及微波吸收研究

Facile synthesis and microwave absorption investigation of activated carbon@FeO composites in the low frequency band.

作者信息

Yin Pengfei, Deng Yu, Zhang Limin, Li Ning, Feng Xing, Wang Jian, Zhang Yi

机构信息

College of Science, Sichuan Agricultural University Ya'an 625014 P. R. China.

College of Water Conservancy and Hydropower Engineering, Sichuan Agricultural University Ya'an 625014 P. R. China

出版信息

RSC Adv. 2018 Jun 25;8(41):23048-23057. doi: 10.1039/c8ra04141e. eCollection 2018 Jun 21.

Abstract

Activated carbon@FeO composites with good electromagnetic wave absorption performances in the low frequency range were synthesized the hydrothermal method. The crystal structure, microstructure, magnetization properties, frequency-dependent electromagnetic properties and microwave absorption properties of the as-prepared composites were characterized XRD, VSM, SEM, TEM and VNA, respectively. The results indicated that the electromagnetic wave absorption performance of the composites can be adjusted through the addition of activated carbon. A suitable loading content of FeO NPs on activated carbon can also enhance the microwave absorption performance of the composites. The synergy of dielectric and magnetic loss is the main electromagnetic wave absorption mechanism, and the maximum RL of -10.08 dB at 1.75 GHz with a -5 dB bandwidth over the frequency range of 1.55 GHz (1.07-2.62 GHz) is obtained when the percentage of FeO NPs and the thickness of the composites are 74 wt% and 5 mm, respectively. Hence, the composite reported in this study can be used as a promising microwave absorbing material in the low frequency range of 0.5-3 GHz.

摘要

通过水热法合成了在低频范围内具有良好电磁波吸收性能的活性炭@FeO复合材料。分别采用XRD、VSM、SEM、TEM和VNA对所制备复合材料的晶体结构、微观结构、磁化性能、频率相关电磁性能和微波吸收性能进行了表征。结果表明,通过添加活性炭可以调节复合材料的电磁波吸收性能。在活性炭上负载合适含量的FeO纳米颗粒也可以提高复合材料的微波吸收性能。介电损耗和磁损耗的协同作用是主要的电磁波吸收机制,当FeO纳米颗粒的百分比和复合材料的厚度分别为74 wt%和5 mm时,在1.75 GHz处获得了-10.08 dB的最大反射损耗,在1.55 GHz(从1.07到2.62 GHz)的频率范围内具有-5 dB的带宽。因此,本研究报道的复合材料可作为0.5-3 GHz低频范围内有前景的微波吸收材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/891e/9081594/939f804d16d3/c8ra04141e-f1.jpg

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