Sun Qilong, Sun Lei, Cai YingYing, Ji Tao, Zhang Guangyu
National & Local Joint Engineering Research Center of Technical Fiber Composites for Safety and Protection, Nantong University Nantong 226019 Jiangsu P. R. China.
College of Textiles and Clothing, Nantong University Nantong 226019 Jiangsu P. R. China
RSC Adv. 2018 Oct 15;8(61):35337-35342. doi: 10.1039/c8ra05872e. eCollection 2018 Oct 10.
To obtain a low-density material that is capable of absorbing electromagnetic waves over a wide bandwidth, an activated carbon fiber/FeO composite material (ACF/FeO) was prepared using an reduction method. Scanning electron microscopy images show that FeO nanoparticles, approximately 10-40 nm in size, were spread uniformly over the surface of the ACF. The resulting composite exhibited superparamagnetic behavior at room temperature. The ability of the ACF and ACF/FeO composite to absorb electromagnetic waves over a frequency range of 8.2-18 GHz was measured using the arch method. The results showed that the maximum reflectivity of an ACF felt was -12.9 dB at 18 GHz, and the effective microwave-absorbing bandwidth ( < -10 dB) was 1.9 GHz (16.10-18 GHz). The absorption performance of the ACF was greatly enhanced by being loaded with FeO nanoparticles; the maximum reflectivity of the 2 mm layer of the ACF/FeO composite was -30.07 dB at 16.45 GHz, and the effective bandwidth ( < -10 dB) increased to 8.62 GHz (9.38-18 GHz). Coating with nano-FeO magnetic particles can effectively improve the absorption of electromagnetic waves by the ACF, and this technique therefore has great potential for application to the field of electromagnetic shielding.
为了获得一种能够在宽频带上吸收电磁波的低密度材料,采用还原法制备了活性炭纤维/FeO复合材料(ACF/FeO)。扫描电子显微镜图像显示,尺寸约为10 - 40 nm的FeO纳米颗粒均匀分布在ACF表面。所得复合材料在室温下表现出超顺磁性行为。使用弓形法测量了ACF和ACF/FeO复合材料在8.2 - 18 GHz频率范围内吸收电磁波的能力。结果表明,ACF毡在18 GHz时的最大反射率为-12.9 dB,有效微波吸收带宽(< -10 dB)为1.9 GHz(16.10 - 18 GHz)。通过负载FeO纳米颗粒,ACF的吸收性能得到了极大增强;ACF/FeO复合材料2 mm层在16.45 GHz时的最大反射率为-30.07 dB,有效带宽(< -10 dB)增加到8.62 GHz(9.38 - 18 GHz)。用纳米FeO磁性颗粒包覆可以有效提高ACF对电磁波的吸收,因此该技术在电磁屏蔽领域具有巨大的应用潜力。