Dutta Basudeb, Purkait Rakesh, Bhunia Suprava, Khan Samim, Sinha Chittaranjan, Mir Mohammad Hedayetullah
Department of Chemistry, Aliah University New Town Kolkata 700 156 India
Department of Chemistry, Jadavpur University Jadavpur Kolkata 700 032 India.
RSC Adv. 2019 Nov 26;9(66):38718-38723. doi: 10.1039/c9ra08614e. eCollection 2019 Nov 25.
A Cd(ii)-based coordination compound, [CdI(4-nvp)] (1), has been synthesized using CdI and monodentate N-donor ligand 4-(1-naphthylvinyl)pyridine (4-nvp). The solid-state supramolecular architecture has been characterized by X-ray crystallography. An acute thermal stability and excellent level of phase purity tempted us to use it for material applications. Interestingly, compound 1 exhibits a high selectivity towards trinitrophenol (TNP) in the presence of other nitroaromatics. Therefore, this material may be used for anti-terrorist activities in the detection of explosive materials as well as in the recognition of TNP in analytical laboratories.
一种基于镉（II）的配位化合物[CdI(4 - nvp)]（1），已通过碘化镉和单齿氮供体配体4 -（1 - 萘基乙烯基）吡啶（4 - nvp）合成。其固态超分子结构已通过X射线晶体学进行了表征。该化合物具有较高的热稳定性和出色的相纯度，这促使我们将其用于材料应用。有趣的是，在存在其他硝基芳烃的情况下，化合物1对三硝基苯酚（TNP）表现出高选择性。因此，这种材料可用于爆炸物检测中的反恐活动以及分析实验室中TNP的识别。
