Kavil Jithesh, Anjana P M, Joshy Deepak, Babu Ameya, Raj Govind, Periyat P, Rakhi R B
Department of Chemistry, University of Calicut Kerala India-673635
Chemical Sciences and Technology Division, CSIR-National Institute of Interdisciplinary Sciences (CSIR-NIIST) Thiruvananthapuram Kerala India 695019
RSC Adv. 2019 Nov 25;9(66):38430-38437. doi: 10.1039/c9ra08979a.
Metal oxide dispersed graphitic carbon nitride hybrid nanocomposites (g-CN/CuO and g-CN/CoO) were prepared a direct precipitation method. The materials were used as an electrode material in symmetric supercapacitors. The g-CN/CoO electrode based device exhibited a specific capacitance of 201 F g which is substantially higher than those using g-CN/CuO (95 F g) and bare g-CN electrodes (72 F g). At a constant power density of 1 kW kg, the energy density given by g-CN/CoO and g-CN/CuO devices is 27.9 W h kg and 13.2 W h kg respectively. The enhancement of the electrochemical performance in the hybrid material is attributed to the pseudo capacitive nature of the metal oxide nanoparticles incorporated in the g-CN matrix.
采用直接沉淀法制备了金属氧化物分散的石墨相氮化碳杂化纳米复合材料(g-CN/CuO和g-CN/CoO)。这些材料被用作对称超级电容器的电极材料。基于g-CN/CoO电极的器件表现出201 F g的比电容,这大大高于使用g-CN/CuO(95 F g)和裸g-CN电极(72 F g)的器件。在1 kW kg的恒定功率密度下,g-CN/CoO和g-CN/CuO器件给出的能量密度分别为27.9 W h kg和13.2 W h kg。杂化材料中电化学性能的增强归因于掺入g-CN基体中的金属氧化物纳米颗粒的赝电容性质。