Advanced Materials and Catalysis Group, ZJU-NHU United R&D Center, Center for Chemistry of High-Performance and Novel Materials, Key Lab of Applied Chemistry of Zhejiang Province, Department of Chemistry, Zhejiang University, Hangzhou (P.R. China).
ChemSusChem. 2015 Mar;8(6):931-46. doi: 10.1002/cssc.201403287. Epub 2015 Feb 16.
With the explosive growth of energy consumption, the exploration of highly efficient energy conversion and storage devices becomes increasingly important. Fuel cells, supercapacitors, and lithium-ion batteries are among the most promising options. The innovation of these devices mainly resides in the development of high-performance electrode materials and catalysts. Graphitic carbon nitride (g-C3 N4 ), due to structural and chemical properties such as semiconductor optical properties, rich nitrogen content, and tunable porous structure, has drawn considerable attention and shown great potential as an electrode material or catalyst in energy conversion and storage devices. This review covers recent progress in g-C3 N4 -containing systems for fuel cells, electrocatalytic water splitting devices, supercapacitors, and lithium-ion batteries. The corresponding catalytic mechanisms and future research directions in these areas are also discussed.
随着能源消耗的爆炸式增长,探索高效的能量转换和存储设备变得越来越重要。燃料电池、超级电容器和锂离子电池是最有前途的选择之一。这些设备的创新主要在于高性能电极材料和催化剂的开发。石墨相氮化碳(g-C3 N4 )由于其半导体光学性质、丰富的氮含量和可调多孔结构等结构和化学性质,作为能量转换和存储设备中的电极材料或催化剂引起了相当大的关注,并显示出巨大的潜力。本综述涵盖了用于燃料电池、电催化水分解装置、超级电容器和锂离子电池的含 g-C3 N4 系统的最新进展。还讨论了这些领域的相应催化机制和未来研究方向。