Wei Laiyun, Fu Xuan, Luo Mingchao, Xie Zhengtian, Huang Cheng, Zhou Junjun, Zhu Yong, Huang Guangsu, Wu Jinrong
State Key Laboratory of Polymer Material Engineering, College of Polymer Science and Engineering, Sichuan University China
RSC Adv. 2018 Mar 15;8(19):10573-10581. doi: 10.1039/c7ra12830d. eCollection 2018 Mar 13.
In this paper, graphene oxide (GO) and carbon nanotube (CNT) hybrid fillers were used to replace partial carbon black (CB), and GO/CNT/CB/NR composites were prepared with excellent crack growth resistance, low heat build-up and superior mechanical properties. Mechanical testing revealed a significant synergistic reinforcement between GO/CNT and CB in NR composites. The improved dispersion of GO/CNT hybrid fillers and CB in the NR matrix was characterized by transmission electron microscopy (TEM). Through the fatigue test, the GO/CNT/CB/NR composites showed excellent fatigue crack growth resistance and low heat build-up compared to CB/NR composites. These properties provide the NR composites with better applications in industry.
在本文中,氧化石墨烯(GO)和碳纳米管(CNT)混合填料被用于替代部分炭黑(CB),并制备了具有优异抗裂纹扩展性能、低生热和卓越力学性能的GO/CNT/CB/NR复合材料。力学测试表明,在天然橡胶(NR)复合材料中,GO/CNT与CB之间存在显著的协同增强作用。通过透射电子显微镜(TEM)对GO/CNT混合填料和CB在NR基体中改善的分散情况进行了表征。通过疲劳试验,与CB/NR复合材料相比,GO/CNT/CB/NR复合材料表现出优异的抗疲劳裂纹扩展性能和低生热性能。这些性能使NR复合材料在工业中具有更好的应用。