Husnain Syed M, Um Wooyong, Chang Yoon-Seok
School of Environmental Science and Engineering, Pohang University of Science and Technology (POSTECH) Pohang 790-784 Republic of Korea.
Division of Advanced Nuclear Engineering, POSTECH Republic of Korea.
RSC Adv. 2018 Jan 11;8(5):2521-2540. doi: 10.1039/c7ra12299c. eCollection 2018 Jan 9.
As a result of extensive research efforts by several research groups, magnetite-based materials have gained enormous attention in diverse fields including biomedicine, catalysis, energy and data storage devices, magnetic resonance imaging, and environmental remediation. Owing to their low production cost, ease of modification, biocompatibility, and superparamagnetism, the use of these materials for the abatement of environmental toxicants has been increasing continuously. Here we focus on the recent advances in the use of magnetite-based adsorbents for removal of radionuclides (such as Cs(i), Eu(iii), Sr(ii), U(vi), ) from diverse aqueous phases. This review summarizes the preparation and surface modification of magnetite-based adsorbents, their physicochemical properties, adsorption behavior and mechanism, and diverse conventional and recent environmental technological options for the treatment of water contaminated with radionuclides. In addition, case studies for the removal of radionuclides from actual contaminated sites are discussed, and finally the optimization of magnetite-based remedial solutions is presented for practical application.
经过多个研究小组的广泛研究,基于磁铁矿的材料在生物医学、催化、能源和数据存储设备、磁共振成像以及环境修复等多个领域受到了极大关注。由于其生产成本低、易于改性、生物相容性好以及超顺磁性,这些材料在减少环境毒物方面的应用一直在持续增加。在此,我们重点关注基于磁铁矿的吸附剂用于从不同水相中去除放射性核素(如铯(Ⅰ)、铕(Ⅲ)、锶(Ⅱ)、铀(Ⅵ)等)的最新进展。本综述总结了基于磁铁矿的吸附剂的制备和表面改性、其物理化学性质、吸附行为和机制,以及用于处理受放射性核素污染水的各种传统和最新环境技术选择。此外,还讨论了从实际污染场地去除放射性核素的案例研究,最后提出了基于磁铁矿的修复解决方案的优化以供实际应用。