Zheng Zilong, Zhang Wenchao, Yu Chunpei, Zheng Guoqiang, Ma Kefeng, Qin Zhichun, Ye Jiahai, Chao Yimin
School of Chemical Engineering, Nanjing University of Science and Technology Nanjing 210094 China
The 43rd Research Institute of CETC Hefei 230088 China.
RSC Adv. 2018 Jan 11;8(5):2552-2560. doi: 10.1039/c7ra11293a. eCollection 2018 Jan 9.
Microigniters play an important role for the reliable initiation of micro explosive devices. However, the microigniter is still limited by the low out-put energy to realize high reliability and safety. Integration of energetic materials with microigniters is an effective method to enhance the ignition ability. In this work, a Al/CoO nanothermite film with a three-dimensionally ordered macroporous structure was prepared by the deposition of nanoscale Al layers using magnetron sputtering on CoO skeletons that are synthesized using an inverse template method. Both the uniform structure and nanoscale contact between the Al layers and the CoO skeletons lead to an excellent exothermicity. In order to investigate the ignition properties, a micro-energetic igniter has been fabricated by the integration of the Al/CoO nanothermite film with a semiconductor bridge microigniter. The thermite reactions between the nanoscale Al layer and the CoO skeleton extensively promote the intensity of the spark, the length in duration and the size of the area, which greatly enhance the ignition reliability of the micro-energetic igniter. Moreover, this novel design enables the micro-energetic igniter to fire the pyrotechnic Zr/PbO in a gap of 3.7 mm by capacitor discharge stimulation and to keep the intrinsic instantaneity high and firing energy low. The realization of gap ignition will surely improve the safety level of initiating systems and have a significant impact on the design and application of explosive devices.
微型点火器对于微型爆炸装置的可靠起爆起着重要作用。然而,微型点火器仍受低输出能量的限制,难以实现高可靠性和安全性。将含能材料与微型点火器相结合是提高点火能力的有效方法。在本工作中,通过磁控溅射在采用反模板法合成的CoO骨架上沉积纳米级Al层,制备了具有三维有序大孔结构的Al/CoO纳米铝热剂薄膜。Al层与CoO骨架之间均匀的结构和纳米级接触导致了优异的放热性能。为了研究点火性能,通过将Al/CoO纳米铝热剂薄膜与半导体桥微型点火器相结合,制备了一种微型含能点火器。纳米级Al层与CoO骨架之间的铝热反应极大地提高了火花强度、持续时间和作用面积,显著提高了微型含能点火器的点火可靠性。此外,这种新颖的设计使微型含能点火器能够通过电容放电激发在3.7 mm的间隙中点燃烟火药剂Zr/PbO,并保持高固有即时性和低发火能量。间隙点火的实现必将提高起爆系统的安全水平,并对爆炸装置的设计和应用产生重大影响。