• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

具有层状结构的新型CeMoO - 粘土杂化催化剂用于NH₃选择性催化还原NO

Novel CeMo O -clay hybrid catalysts with layered structure for selective catalytic reduction of NO by NH.

作者信息

Xu Boyang, Liu Youlin, Shen Yuesong, Zhu Shemin

机构信息

College of Materials Science and Engineering, Nanjing Tech University Nanjing 210009 China

Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Nanjing Tech University Nanjing 210009 China.

出版信息

RSC Adv. 2018 Jan 11;8(5):2586-2592. doi: 10.1039/c7ra12153a. eCollection 2018 Jan 9.

DOI:10.1039/c7ra12153a
PMID:35541496
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9077446/
Abstract

A facile method is to prepare novel CeMo O -clay hybrid catalysts with layered structures by using organic cation modified clay as support. During the preparation process, cerium cations and molybdate anions are easily adsorbed and impregnated into the interlamellar space of the organoclay, and after calcination they undergo transformation to highly dispersed CeMo O nanoparticles within the interlamellar space of the clay. As expected, the prepared CeMoO -OC- catalysts with layered structures had high selective catalytic reduction (SCR) activity such as high NO conversion of >90% in the wide temperature range of 220-420 °C. Meanwhile, they also exhibit high stability and tolerance to water vapor (5 vol%) and SO (200 ppm), demonstrating that these novel catalysts could serve as a good alternative for NH-SCR in practical application.

摘要

一种简便的方法是使用有机阳离子改性粘土作为载体来制备具有层状结构的新型CeMoO -粘土杂化催化剂。在制备过程中，铈阳离子和钼酸根阴离子很容易被吸附并浸渍到有机粘土的层间空间中，经过煅烧后，它们在粘土层间空间内转化为高度分散的CeMoO纳米颗粒。正如预期的那样，制备的具有层状结构的CeMoO -OC-催化剂具有高选择性催化还原（SCR）活性，例如在220-420°C的宽温度范围内具有>90%的高NO转化率。同时，它们还表现出对水蒸气（5 vol%）和SO（200 ppm）的高稳定性和耐受性，表明这些新型催化剂在实际应用中可以作为NH-SCR的良好替代品。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/a937e41aee4c/c7ra12153a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/b67b21a471e9/c7ra12153a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/c1448a831e30/c7ra12153a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/e2ccbd7d7771/c7ra12153a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/51e3cf59f54d/c7ra12153a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/ec1a83bfea8f/c7ra12153a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/556642433e4c/c7ra12153a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/65b7228e7928/c7ra12153a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/78b77ca20606/c7ra12153a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/a937e41aee4c/c7ra12153a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/b67b21a471e9/c7ra12153a-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/c1448a831e30/c7ra12153a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/e2ccbd7d7771/c7ra12153a-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/51e3cf59f54d/c7ra12153a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/ec1a83bfea8f/c7ra12153a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/556642433e4c/c7ra12153a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/65b7228e7928/c7ra12153a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/78b77ca20606/c7ra12153a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d98e/9077446/a937e41aee4c/c7ra12153a-f8.jpg

相似文献

1
Novel CeMo O -clay hybrid catalysts with layered structure for selective catalytic reduction of NO by NH.具有层状结构的新型CeMoO - 粘土杂化催化剂用于NH₃选择性催化还原NO
RSC Adv. 2018 Jan 11;8(5):2586-2592. doi: 10.1039/c7ra12153a. eCollection 2018 Jan 9.
2
Highly selective catalytic reduction of NO by MnO-CeO-AlO catalysts prepared by self-propagating high-temperature synthesis.自蔓延高温合成法制备的 MnO-CeO-AlO 催化剂对 NO 的高选择性催化还原。
J Environ Sci (China). 2019 Jan;75:124-135. doi: 10.1016/j.jes.2018.03.011. Epub 2018 Mar 17.
3
Improved NO Reduction in the Presence of SO by Using FeO-Promoted Halloysite-Supported CeO-WO Catalysts.利用 FeO 促进的埃洛石负载 CeO-WO 催化剂提高 SO 存在下的 NO 还原。
Environ Sci Technol. 2019 Jan 15;53(2):938-945. doi: 10.1021/acs.est.8b05637. Epub 2019 Jan 7.
4
A novel CNTs functionalized CeO/CNTs-GAC catalyst with high NO conversion and SO tolerance for low temperature selective catalytic reduction of NO by NH.一种新型 CNTs 功能化 CeO/CNTs-GAC 催化剂，具有高 NO 转化率和 SO2 耐受性，用于 NH3 低温选择性催化还原 NO。
Chemosphere. 2021 Dec;284:131377. doi: 10.1016/j.chemosphere.2021.131377. Epub 2021 Jun 28.
5
VxMn(4-x)Mo3Ce3/Ti catalysts for selective catalytic reduction of NO by NH.VxMn(4-x)Mo3Ce3/Ti 催化剂用于 NH3 选择性催化还原 NO。
J Environ Sci (China). 2020 Feb;88:145-154. doi: 10.1016/j.jes.2019.07.010. Epub 2019 Jul 22.
6
Effect of Indium Addition on the Low-Temperature Selective Catalytic Reduction of NO by NH over MnCeO Catalysts: The Promotion Effect and Mechanism.铟添加对MnCeO催化剂上NH低温选择性催化还原NO的影响：促进作用及机理
ACS Omega. 2022 Feb 8;7(7):6381-6392. doi: 10.1021/acsomega.1c07000. eCollection 2022 Feb 22.
7
A comparative study on the Mn/TiO-M(M = Sn, Zr or Al) O catalysts for NH-SCR reaction at low temperature.用于低温NH-SCR反应的Mn/TiO-M（M = Sn、Zr或Al）O催化剂的对比研究
Environ Technol. 2018 May;39(10):1284-1294. doi: 10.1080/21622515.2017.1329345. Epub 2017 May 29.
8
Selective catalytic reduction of NO by low-temperature NH over Mn Zr mixed-oxide catalysts.锰锆混合氧化物催化剂上低温NH3选择性催化还原NO
RSC Adv. 2022 Jan 6;12(3):1341-1351. doi: 10.1039/d1ra08800a. eCollection 2022 Jan 5.
9
Insight into the promoting effect of support pretreatment with sulfate acid on selective catalytic reduction performance of CeO/ZrO catalysts.深入了解硫酸预处理对 CeO/ZrO2 催化剂选择性催化还原性能的促进作用。
J Colloid Interface Sci. 2022 Feb 15;608(Pt 3):2718-2729. doi: 10.1016/j.jcis.2021.10.191. Epub 2021 Nov 5.
10
Low-temperature SCR of NO by NH over MnO/SAPO-34 prepared by two different methods: a comparative study.通过两种不同方法制备的MnO/SAPO-34上NH3低温选择性催化还原NO：对比研究
Environ Technol. 2017 Apr;38(8):1030-1042. doi: 10.1080/09593330.2016.1216170. Epub 2016 Aug 9.

本文引用的文献

1
CeO nanowires self-inserted into porous CoO frameworks as high-performance "noble metal free" hetero-catalysts.氧化铈纳米线自插入多孔氧化钴框架中，作为高性能的“无贵金属”异质催化剂。
Chem Sci. 2016 Feb 1;7(2):1109-1114. doi: 10.1039/c5sc03430b. Epub 2015 Oct 28.
2
Efficient NH-SCR removal of NO with highly ordered mesoporous WO(χ)-CeO at low temperatures.在低温下利用高度有序的介孔WO(χ)-CeO通过高效NH-SCR去除NO
Appl Catal B. 2017 Apr;203:199-209. doi: 10.1016/j.apcatb.2016.10.010. Epub 2016 Oct 13.
3
Simultaneous Removal of NO and Hg(0) from Flue Gas over Mn-Ce/Ti-PILCs.
Mn-Ce/Ti-PILCs 上同时脱除烟气中的 NO 和 Hg(0)。
Environ Sci Technol. 2015 Aug 4;49(15):9355-63. doi: 10.1021/acs.est.5b01435. Epub 2015 Jul 22.
4
Significant Promotion Effect of Mo Additive on a Novel Ce-Zr Mixed Oxide Catalyst for the Selective Catalytic Reduction of NO(x) with NH3.钼添加剂对新型 Ce-Zr 混合氧化物催化剂用于 NH3 选择性催化还原 NO(x)的显著促进作用。
ACS Appl Mater Interfaces. 2015 May 13;7(18):9497-506. doi: 10.1021/acsami.5b00636. Epub 2015 Apr 29.
5
Effect of Ce doping of TiO2 support on NH3-SCR activity over V2O5-WO3/CeO2-TiO2 catalyst.Ce 掺杂 TiO2 载体对 V2O5-WO3/CeO2-TiO2 催化剂上 NH3-SCR 活性的影响。
J Environ Sci (China). 2014 Oct 1;26(10):2106-13. doi: 10.1016/j.jes.2014.08.010. Epub 2014 Aug 11.
6
Deactivation mechanism of potassium on the V₂O₅/CeO₂ catalysts for SCR reaction: acidity, reducibility and adsorbed-NOx.钾在 V₂O₅/CeO₂ 催化剂上对 SCR 反应的失活动力学：酸度、还原性和吸附态-NOx。
Environ Sci Technol. 2014 Apr 15;48(8):4515-20. doi: 10.1021/es405602a. Epub 2014 Mar 28.