钌催化的硫代碳酸酯脱羧C-S交叉偶联反应：烯丙基（芳基）硫醚的合成
Ruthenium-catalyzed decarboxylative C-S cross-coupling of carbonothioate: synthesis of allyl(aryl)sulfide.
作者信息
Zheng Ren-Hua, Guo Hai-Chang, Chen Ting-Ting, Huang Qing, Huang Guo-Bo, Jiang Hua-Jiang
机构信息
School of Pharmaceutical and Chemical Engineering, Taizhou University Taizhou 318000 China
College of Pharmaceutical Science, Zhejiang University of Technology Hangzhou 310014 China.
出版信息
RSC Adv. 2018 Jul 12;8(44):25123-25126. doi: 10.1039/c8ra04783a. eCollection 2018 Jul 9.
A novel ruthenium-catalyzed decarboxylative cross-coupling of carbonothioate is disclosed. This method provides straightforward access to the corresponding allyl(aryl)sulfide derivatives in generally good to excellent yields under mild conditions and features a broad substrate scope, wide group tolerance and in particular, no need to use halocarbon precursors.
公开了一种新型钌催化的硫代碳酸酯脱羧交叉偶联反应。该方法能在温和条件下直接得到相应的烯丙基（芳基）硫醚衍生物，产率通常良好至优异，具有底物范围广、基团耐受性强的特点，尤其无需使用卤代烃前体。
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