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用于光捕获应用的BODIPY-苯乙炔大环二元化合物的光物理行为。

Photophysical behaviour of BODIPY-phenylacetylene macrocyclic dyads for light-harvesting applications.

作者信息

Yousaf Muhammad, Zarate Ximena, Schott Eduardo, Lough Alan J, Koivisto Bryan D

机构信息

Department of Chemistry and Biology, Ryerson University 350 Victoria St Toronto Canada

Institute of Chemistry, University of the Punjab, Quaid-i-Azam Campus Lahore-54590 Pakistan.

出版信息

RSC Adv. 2018 Aug 10;8(50):28533-28537. doi: 10.1039/c8ra03384f. eCollection 2018 Aug 7.

Abstract

The synthesis and study of a family of BODIPY-phenylacetylene macrocycles where donor groups have been added to the macrocycle in order to tune the physicochemical properties and absorption profile is reported. Energy transfer is observed between this phenylacetylene antennae and BODIPY core and fluorescence emission from the BODIPY, at any excitation wavelength, is consistent with energy transfer from the macrocycle.

摘要

报道了一系列BODIPY-苯乙炔大环化合物的合成与研究,其中在大环上添加了供体基团以调节其物理化学性质和吸收光谱。观察到该苯乙炔天线与BODIPY核心之间存在能量转移,并且在任何激发波长下,BODIPY的荧光发射都与来自大环的能量转移一致。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9e48/9083918/616706c2c554/c8ra03384f-f1.jpg

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