Xu Xinya, Qu Yongtao, Barrioz Vincent, Zoppi Guillaume, Beattie Neil S
Department of Mathematics, Physics and Electrical Engineering, Northumbria University Newcastle-upon-Tyne NE1 8ST UK
RSC Adv. 2018 Jan 17;8(7):3470-3476. doi: 10.1039/c7ra13336g. eCollection 2018 Jan 16.
Earth abundant CuZnSnS nanoparticle inks were deposited on molybdenum foil substrates and subsequently converted to high quality thin film CuZnSn(S,Se) photovoltaic absorbers. Integration of these absorbers within a thin film solar cell device structure yields a solar energy conversion efficiency which is comparable to identical devices processed on rigid glass substrates. Importantly, this is only achieved when a thin layer of molybdenum is first applied directly to the foil. The layer limits the formation of a thick Mo(S,Se) layer resulting in a substantially reduced series resistance.
将地球上储量丰富的铜锌锡硫纳米颗粒墨水沉积在钼箔基板上,随后将其转化为高质量的薄膜铜锌锡(硫,硒)光伏吸收层。将这些吸收层集成到薄膜太阳能电池器件结构中,可实现与在刚性玻璃基板上加工的相同器件相当的太阳能转换效率。重要的是,只有在首先将一层薄钼直接涂覆在箔上时才能实现这一点。该层限制了厚钼(硫,硒)层的形成,从而显著降低了串联电阻。