乙烯与非乙烯基极性单体的共聚。

Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo.

Proc Jpn Acad Ser B Phys Biol Sci. 2022;98(5):222-226. doi: 10.2183/pjab.98.014.

Introduction of functional groups on polyethylene endows it with a higher surface property and thus various catalysts have been developed for the copolymerization of ethylene with polar vinyl monomers. Aside from vinyl monomers, however, other classes of polar monomers have not found application in the copolymerization with ethylene. Here, in this short review article, our latest studies on catalyst development aiming at the use of non-vinyl polar monomers and the properties of the resulting copolymers are summarized.

在聚乙烯的末端引入官能团可以赋予其更高的表面性能，因此已经开发出各种催化剂用于乙烯与极性乙烯基单体的共聚。然而，除了乙烯基单体之外，其他类别的极性单体尚未在与乙烯的共聚中得到应用。在这篇简短的综述文章中，我们总结了最新的关于旨在使用非乙烯基极性单体的催化剂开发和所得共聚物的性能的研究。