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质子和离子束辐照的弯曲聚合物板的表面分析

Surface analysis of curved polymeric plates irradiated with proton and ion beams.

作者信息

Song Young Seok, Kang Chul, Jeong Jiwon, Kim Minji, Lim Eunju

机构信息

Department of Fiber System Engineering, Dankook University Yongin 448-701 Korea.

Department of Science Education/Creative Convergence Manufacturing Engineering, Dankook University Yongin 448-701 Korea

出版信息

RSC Adv. 2018 Oct 11;8(61):34895-34902. doi: 10.1039/c8ra06636a. eCollection 2018 Oct 10.

DOI:10.1039/c8ra06636a
PMID:35547031
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9087293/
Abstract

We explored surface characteristics of polycarbonate substrates which were subjected to proton and nitrogen ion beams. Curved plates designed for a plastic window of a cell phone were fabricated using injection molding, and the process was simulated numerically. Different energy densities of proton and nitrogen ion beams were applied in this study. The physical and chemical properties of the samples were evaluated using UV-Vis spectroscopy, FT-IR, differential scanning calorimetry (DSC), nanoindentation, residual stress, and electrical analyses. Results revealed that the irradiation of proton and nitrogen ion beams led to changes in the chemical structures and energy levels of the polymer molecules. Furthermore, physical properties, such as hardness, glass transition temperature, transmittance, and electrical conductivity, were remarkably varied.

摘要

我们探究了经过质子和氮离子束处理的聚碳酸酯基板的表面特性。通过注塑成型制造了用于手机塑料窗口的弯曲板,并对该过程进行了数值模拟。本研究中应用了不同能量密度的质子和氮离子束。使用紫外可见光谱、傅里叶变换红外光谱、差示扫描量热法(DSC)、纳米压痕、残余应力和电学分析对样品的物理和化学性质进行了评估。结果表明,质子和氮离子束的辐照导致聚合物分子的化学结构和能级发生变化。此外,硬度、玻璃化转变温度、透光率和电导率等物理性质也有显著变化。

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本文引用的文献

1
Focused Electron and Ion Beam Induced Deposition on Flexible and Transparent Polycarbonate Substrates.聚焦电子束和离子束诱导沉积在柔性透明聚碳酸酯基底上。
ACS Nano. 2015 Jun 23;9(6):6139-46. doi: 10.1021/acsnano.5b01383. Epub 2015 Jun 8.
2
Modifications induced by gamma irradiation to Makrofol polymer nuclear track detector.伽马射线辐照对 Makrofol 聚合物核径迹探测器的改性。
J Adv Res. 2015 Mar;6(2):219-24. doi: 10.1016/j.jare.2014.01.005. Epub 2014 Jan 18.
3
Surface structure and apatite-forming ability of polyethylene substrates irradiated by oxygen cluster ion beams.
氧簇离子束辐照的聚乙烯基底的表面结构及磷灰石形成能力
J Biomed Mater Res A. 2007 Sep 15;82(4):995-1003. doi: 10.1002/jbm.a.31253.