NiO/Ni Co O porous ultrathin nanosheet/nanowire composite structures as high-performance supercapacitor electrodes.

The demand for a new generation of high-safety, long-lifespan, and high-capacity power sources increases rapidly with the growth of energy consumption in the world. Here we report a facile method for preparing architecture materials made of NiO/Ni Co O porous nanosheets coupled with NiO/Ni Co O porous nanowires grown on nickel foams using a hydrothermal method without any binder followed by a heat treatment process. The nanosheet-shaped NiO/Ni Co O species in the nanosheet matrix function well as a scaffold and support for the dispersion of the Ni Co O nanowires, resulting in a relatively loose and open structure within the electrode matrix. Among all composite electrodes prepared, the one annealed in air at 300 °C displays the best electrochemical behavior, achieving a specific capacitance of 270 mF cm at 5 mA cm while maintaining excellent stability (retaining ≈ 89% of the max capacitance after 20 000 cycles), demonstrating its potential for practical application in power storage devices.