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通过湿法冶金路线从废旧碱性电池制备ZnMnO：合成与表征

From spent alkaline batteries to Zn Mn O by a hydrometallurgical route: synthesis and characterization.

作者信息

Romo Lorena Alcaraz, López-Fernández Ana, García-Díaz Irene, Fernández Paloma, Urbieta Ana, López Félix A

机构信息

Centro Nacional de Investigaciones Metalúrgicas (CENIM-CSIC) Avda. Gregorio del Amo 8 28040 Madrid Spain

Facultad de Ciencias Físicas, Universidad Complutense de Madrid, Ciudad Universitaria Plaza de las Ciencias 28040 Madrid Spain.

出版信息

RSC Adv. 2018 Sep 28;8(58):33496-33505. doi: 10.1039/c8ra06789a. eCollection 2018 Sep 24.

DOI:10.1039/c8ra06789a
PMID:35548165
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9086476/
Abstract

A series of Zn/Mn binary oxides with different molar ratios (1.4-11) were synthesized co-precipitation from a solution obtained through the acidic (HCl) leaching of a black mass originating from the mechanical recycling of spent alkaline and Zn-C batteries. The oxides obtained were characterized by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. Magnetic properties of the samples were also investigated. The Raman spectroscopy results showed all the binary metallic oxides belong to the Zn Mn O (0.25 ≤ ≥ 1.75) type. All showed a spinel crystalline structure. The saturation magnetization decreases with the Zn/Mn molar ratio; a maximum of 13.19 emu g was found for the molar ratio of 11 at the Curie temperature (25.5 K). XPS showed that all the synthesized compounds contained Mn, Mn and Mn. Mn was the most prominent at a molar ratio of 11, Mn was most common at a molar ratio of 2, and Mn at 1.4.

摘要

通过对废旧碱性电池和锌碳电池机械回收得到的黑色物质进行酸性（盐酸）浸出，从所得溶液中通过共沉淀法合成了一系列不同摩尔比（1.4 - 11）的锌/锰二元氧化物。对所得氧化物进行了X射线衍射（XRD）、傅里叶变换红外光谱（FTIR）、X射线光电子能谱（XPS）和拉曼光谱表征。还研究了样品的磁性。拉曼光谱结果表明，所有二元金属氧化物均属于ZnₓMnO₍₀.₂₅ ≤ ₓ ≥ 1.75₎类型。所有样品均呈现尖晶石晶体结构。饱和磁化强度随锌/锰摩尔比降低；在居里温度（25.5 K）下，摩尔比为11时饱和磁化强度最大值为13.19 emu/g。XPS表明，所有合成化合物均含有Mn²⁺、Mn³⁺和Mn⁴⁺。在摩尔比为11时，Mn²⁺最为突出；在摩尔比为2时，Mn³⁺最为常见；在摩尔比为1.4时，Mn⁴⁺最为常见。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/ce7194c8f604/c8ra06789a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/05c2ac265152/c8ra06789a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/7600f46b9bd2/c8ra06789a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/63ff1935aaf5/c8ra06789a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/ec128e3061c8/c8ra06789a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/9e72c933f10c/c8ra06789a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/a077d8c9029a/c8ra06789a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/ce7194c8f604/c8ra06789a-f8.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/05c2ac265152/c8ra06789a-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/7600f46b9bd2/c8ra06789a-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/63ff1935aaf5/c8ra06789a-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/ec128e3061c8/c8ra06789a-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/9e72c933f10c/c8ra06789a-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/a077d8c9029a/c8ra06789a-f7.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9057/9086476/ce7194c8f604/c8ra06789a-f8.jpg

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