Zhang Yongyong, Jia Ying, Hou Li'an
Xi'an High Technology Institute Xi'an 710025 China
RSC Adv. 2018 Sep 7;8(55):31471-31477. doi: 10.1039/c8ra06414h. eCollection 2018 Sep 5.
Zeolitic imidazolate framework-8 (ZIF-8) was introduced on the surface of fibers of a non-woven fabric made of polyethylene terephthalate (PET). The phase structure, morphology, textural properties and chemical structure were studied using X-ray diffraction (XRD), scanning electron microscopy (SEM), nitrogen (N) adsorption analyzer and Fourier transform infrared spectroscopy (FTIR). The XRD, SEM and FTIR results indicated that ZIF-8 had been successfully coated on the PET fibers. N adsorption analyses suggested that addition of ZIF-8 significantly increased the specific surface and micropore volume of composites. The PM removal experiment showed the filtration efficiency of ZIF-8/PET was twice as high as that of pure PET. Meanwhile, ZIF-8/PET also displayed a low pressure drop and good recycling performance. This research provided a facile method to deposit active ZIF-8 onto polymers with low air resistance, and that ZIF-8/PET was a good candidate as an air filter for PM removal.
将咪唑沸石框架-8(ZIF-8)引入到由聚对苯二甲酸乙二酯(PET)制成的无纺布纤维表面。使用X射线衍射(XRD)、扫描电子显微镜(SEM)、氮(N)吸附分析仪和傅里叶变换红外光谱(FTIR)研究了其相结构、形态、织构性质和化学结构。XRD、SEM和FTIR结果表明ZIF-8已成功包覆在PET纤维上。N吸附分析表明,添加ZIF-8显著增加了复合材料的比表面积和微孔体积。PM去除实验表明,ZIF-8/PET的过滤效率是纯PET的两倍。同时,ZIF-8/PET还表现出低压降和良好的循环性能。本研究提供了一种将活性ZIF-8沉积到低空气阻力聚合物上的简便方法,并且ZIF-8/PET是一种用于去除PM的空气过滤器的良好候选材料。