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基于卟啉配体的铜或锌超分子配合物对两种析氧电催化剂的比较

Comparison of two water oxidation electrocatalysts by copper or zinc supermolecule complexes based on porphyrin ligand.

作者信息

Huang Zhaodi, Zhang Meixi, Lin Huan, Ding Shuo, Dong Bin, Liu Di, Wang Hong, Dai Fangna, Sun Daofeng

机构信息

School of Materials Science and Engineering, College of Science, China University of Petroleum (East China) Qingdao Shandong 266580 People's Republic of China.

School of Chemical and Environmental Engineering, Shandong University of Science and Technology Qingdao Shandong 266590 People's Republic of China

出版信息

RSC Adv. 2018 Nov 30;8(70):40054-40059. doi: 10.1039/c8ra08338j. eCollection 2018 Nov 28.

DOI:10.1039/c8ra08338j
PMID:35558199
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9091322/
Abstract

Based on the 5,10,15,20-tetra(cyanophenyl)porphyrin (CNTCPP) ligand, two supermolecule complexes formulated as [Cu(CNTCPP)]·2DMF (Cu-CNTCPP) and [Zn(CNTCPP)] (Zn-CNTCPP) have been synthesized and structurally characterized by single-crystal X-ray diffraction. Cu-CNTCPP features a 0 dimensional (0D) supramoleculer structure, whereas Zn-CNTCPP is a 2D structure. With coordination unsaturated points, Cu-CNTCPP exhibits electrocatalytic activity toward oxygen evolution reaction (OER) with low potential in 1.0 M KOH, generating a current density of 10 mA cm at an potential of 1.66 V RHE, which means it an efficient electrocatalytic material for OER.

摘要

基于5,10,15,20-四（氰基苯基）卟啉（CNTCPP）配体，已合成了两种超分子配合物，其化学式分别为[Cu(CNTCPP)]·2DMF（Cu-CNTCPP）和[Zn(CNTCPP)]（Zn-CNTCPP），并通过单晶X射线衍射对其结构进行了表征。Cu-CNTCPP具有零维（0D）超分子结构，而Zn-CNTCPP是二维结构。由于具有配位不饱和点，Cu-CNTCPP在1.0 M KOH中对析氧反应（OER）表现出低电位的电催化活性，在1.66 V RHE的电位下产生10 mA cm的电流密度，这意味着它是一种用于OER的高效电催化材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/b01e341dd20f/c8ra08338j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/311aa99bd63b/c8ra08338j-f1.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/508542779e71/c8ra08338j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/b8fef6b255ea/c8ra08338j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/b3db58558bac/c8ra08338j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/446654a348e3/c8ra08338j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/b01e341dd20f/c8ra08338j-s1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/311aa99bd63b/c8ra08338j-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/1daedc2b03cb/c8ra08338j-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/508542779e71/c8ra08338j-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/b8fef6b255ea/c8ra08338j-f4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/b3db58558bac/c8ra08338j-f5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/446654a348e3/c8ra08338j-f6.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/9091322/b01e341dd20f/c8ra08338j-s1.jpg

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