Shi Lulu, Jin Lihua, Meng Zheng, Sun Yanan, Li Cong, Shen Yehua
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry & Materials Science, Northwest University Xi'an 710127 People's Republic of China
National Demonstration Center for Experimental Chemistry Education, Northwest University Xi'an 710127 People's Republic of China.
RSC Adv. 2018 Nov 29;8(70):39937-39947. doi: 10.1039/c8ra08664h. eCollection 2018 Nov 28.
The exploitation of efficient renewable energy resources and the promotion of added value of agricultural products are always hot topics. In this study, we present a novel porous carbon material for high performance supercapacitor applications made from the byproduct of bean curd stick manufacture. The as-prepared carbon material possesses a hollow interconnected structure with a large specific surface area (2609 m g), while containing 5.01% oxygen and 1.75% nitrogen heteroatoms. Therefore, besides electrical double-layer capacitance, it can also produce additional pseudocapacitance to enhance the overall capacitance. Benefiting from these advantages of structure and composition, the bean curd stick based porous carbon material demonstrates a high specific capacitance of 405 F g at 0.5 A g. Moreover, the presented porous carbon material based symmetric supercapacitor also offers a high energy density (11.35 W h kg at a power density of 125 W kg). All the above findings indicate that the byproduct of bean curd stick manufacture is an excellent optional material for preparing high-performance supercapacitor material. Simultaneously, this work also provides an effective strategy for adding value to agricultural products.
高效可再生能源资源的开发以及农产品附加值的提升一直都是热门话题。在本研究中,我们展示了一种由腐竹生产副产品制备的、用于高性能超级电容器应用的新型多孔碳材料。所制备的碳材料具有中空互连结构,比表面积大(2609 m²/g),同时含有5.01%的氧和1.75%的氮杂原子。因此,除了双电层电容外,它还能产生额外的赝电容以增强整体电容。得益于结构和组成的这些优势,基于腐竹的多孔碳材料在0.5 A/g电流密度下展现出405 F/g的高比电容。此外,所展示的基于多孔碳材料的对称超级电容器在功率密度为125 W/kg时还具有11.35 W·h/kg的高能量密度。上述所有发现表明,腐竹生产副产品是制备高性能超级电容器材料的优异可选材料。同时,这项工作也为农产品增值提供了一种有效策略。