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硫、钕双掺杂纳米二氧化钛光催化剂的制备及其光催化应用

Preparation and photocatalytic application of a S, Nd double doped nano-TiO photocatalyst.

作者信息

Wang Shuo, Bai Liming, Ao Xinling

机构信息

College of Chemistry and Chemical Engineering, Qiqihar University Qiqihar Heilongjiang 161006 P. R. China

出版信息

RSC Adv. 2018 Oct 31;8(64):36745-36753. doi: 10.1039/c8ra06778c. eCollection 2018 Oct 26.

Abstract

Nowadays, water pollution is getting more and more severe in society, and recently the rational use of photocatalytic technology to treat sewage has become a hot spot for research. Because of the low-cost and environmental friendliness of nano-TiO, it has attracted widespread attention. In this paper, we dope sulfur and neodymium into nano-titanium dioxide a sol-gel method. The synthesized S, Nd-codoped-TiO was characterized transmission electron microscopy, scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, EDS and N adsorption-desorption isotherms. Then the real-life dye reactive red (X-3B) was used as the target degradant to compare the levels of practicality of single-doped and double-doped photocatalysts. The results showed that the photocatalytic activity of S, Nd-codoped-TiO was significantly higher than that of Nd-TiO. The double-doped photocatalyst was transformed from anatase to rutile, and the bandgap was reduced considerably. The responding ability to visible light also increased, so S, Nd-codoped-TiO has obvious advantages and has better degradation efficiency for the target degradation products. Under xenon lamp irradiation and pH = 4 conditions, the degradation of reactive red using the new catalyst reached 93.2%. The new catalyst has high practicality and also indicates a new direction for wastewater treatment.

摘要

如今,水污染在社会中日益严重,近来合理运用光催化技术处理污水已成为研究热点。由于纳米二氧化钛成本低且环保,已引起广泛关注。本文采用溶胶 - 凝胶法将硫和钕掺杂到纳米二氧化钛中。对合成的硫、钕共掺杂二氧化钛进行了透射电子显微镜、扫描电子显微镜、X射线衍射、X射线光电子能谱、能谱仪和氮吸附 - 脱附等温线表征。然后以实际生活中的染料活性红(X - 3B)作为目标降解物,比较单掺杂和双掺杂光催化剂的实用性水平。结果表明,硫、钕共掺杂二氧化钛的光催化活性显著高于钕掺杂二氧化钛。双掺杂光催化剂从锐钛矿转变为金红石型,且带隙大幅减小。对可见光的响应能力也增强,所以硫、钕共掺杂二氧化钛具有明显优势,对目标降解产物具有更好的降解效率。在氙灯照射和pH = 4条件下,使用新型催化剂对活性红的降解率达到93.2%。新型催化剂具有很高的实用性,也为废水处理指明了新方向。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d0b/9088756/d6d88b8123d8/c8ra06778c-f1.jpg

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