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新型氟代硝酸酯含能增塑剂的简易绿色合成

Simple and Green Synthesis of a Novel Fluoro-Nitrato Energetic Plasticizer.

作者信息

Keerthi Harish Kumar, Dey Saheli, Bogaraju Ramakrishna, Maroju Satheesh, Barkakaty Balaka

机构信息

Advanced Centre of Research in High Energy Materials (ACRHEM), University of Hyderabad, Gachibowli, Hyderabad, Telangana 500046, India.

出版信息

ACS Omega. 2022 Apr 13;7(16):14239-14243. doi: 10.1021/acsomega.2c00808. eCollection 2022 Apr 26.

DOI:10.1021/acsomega.2c00808
PMID:35559203
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9089367/
Abstract

Herein, we report a facile, simple, cost-effective, and green synthesis of a new fluoro-nitrato energetic plasticizer, 2-nitrato-1,3-di(trifluoroethoxy)propane (ACR-ENP-1). Compatible mixtures of ACR-ENP-1 with known binders demonstrated far impressive energetic and mechanical properties of the composite compared to similar composites of same binders with known energetic platicizers.

摘要

在此，我们报道了一种简便、简单、经济高效且绿色的新型含氟硝酸酯高能增塑剂2-硝酸酯基-1,3-二（三氟乙氧基）丙烷（ACR-ENP-1）的合成方法。与相同粘合剂和已知高能增塑剂的类似复合材料相比，ACR-ENP-1与已知粘合剂的相容混合物表现出令人印象深刻得多的复合材料的能量和力学性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/6dde5a1d74cb/ao2c00808_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/328bafd981da/ao2c00808_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/53b38cba0865/ao2c00808_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/dc1766fe51b4/ao2c00808_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/6dde5a1d74cb/ao2c00808_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/328bafd981da/ao2c00808_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/53b38cba0865/ao2c00808_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/dc1766fe51b4/ao2c00808_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/158b/9089367/6dde5a1d74cb/ao2c00808_0004.jpg

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本文引用的文献

1
Review of novel energetic polymers and binders - high energy propellant ingredients for the new space race.新型含能聚合物和黏合剂综述——新太空竞赛中的高能推进剂成分
Des Monomers Polym. 2019 Mar 1;22(1):54-65. doi: 10.1080/15685551.2019.1575652. eCollection 2019.