• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

新型含能聚合物和黏合剂综述——新太空竞赛中的高能推进剂成分

Review of novel energetic polymers and binders - high energy propellant ingredients for the new space race.

作者信息

Cheng Tianze

机构信息

Pitzer College, Claremont, CA, USA.

出版信息

Des Monomers Polym. 2019 Mar 1;22(1):54-65. doi: 10.1080/15685551.2019.1575652. eCollection 2019.

DOI:10.1080/15685551.2019.1575652
PMID:30863243
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6407582/
Abstract

Current solid rocket propellant formulations still employ traditional ingredients utilized since the 1960s, such as hydroxyl terminated polybutadiene (HTPB). Recent advances in energetic polymer see many binders capable of providing higher specific impulse and burn rates over HTPB. As shown by calculations, even slight increases in specific impulse can drastically increase the maximum payload of a launch system. Therefore, replacing HTPB with energetic binders could provide heavy space missions the needed extra boost. Energetic binders could also be paired with chlorine-free energetic oxidizers to synergistically provide a specific impulse exceedingly higher than the current formulation while reducing pollution. A comprehensive evaluation of the synthesis, mechanical properties, and performance of various trending and overlooked energetic polymers is described. Several outstanding candidates show promising properties to replace HTPB.

摘要

当前的固体火箭推进剂配方仍采用自20世纪60年代以来使用的传统成分，如端羟基聚丁二烯（HTPB）。高能聚合物的最新进展表明，许多粘合剂能够提供比HTPB更高的比冲和燃烧速率。计算表明，即使比冲略有增加，也能大幅提高发射系统的最大载荷。因此，用高能粘合剂取代HTPB可为重型太空任务提供所需的额外推力。高能粘合剂还可与无氯高能氧化剂配合使用，协同提供比当前配方高得多的比冲，同时减少污染。本文描述了对各种热门和被忽视的高能聚合物的合成、机械性能和性能的综合评估。几种优秀的候选物显示出有望取代HTPB的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/8460629e57ad/TDMP_A_1575652_F0012_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/940387d4fc5c/TDMP_A_1575652_F0001_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/3937e1f0c472/TDMP_A_1575652_F0002_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/4ea1c67885ca/TDMP_A_1575652_F0003_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/18123b2ce7d1/TDMP_A_1575652_F0004_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/590b07a7420e/TDMP_A_1575652_F0005_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/838e57b90d89/TDMP_A_1575652_F0006_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/8bef81554ef5/TDMP_A_1575652_F0007_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/dc05739db0a4/TDMP_A_1575652_F0008_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/5b43f8af330c/TDMP_A_1575652_F0009_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/cae0d2dbbfdc/TDMP_A_1575652_F0010_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/872c830d1d1c/TDMP_A_1575652_F0011_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/8460629e57ad/TDMP_A_1575652_F0012_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/940387d4fc5c/TDMP_A_1575652_F0001_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/3937e1f0c472/TDMP_A_1575652_F0002_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/4ea1c67885ca/TDMP_A_1575652_F0003_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/18123b2ce7d1/TDMP_A_1575652_F0004_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/590b07a7420e/TDMP_A_1575652_F0005_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/838e57b90d89/TDMP_A_1575652_F0006_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/8bef81554ef5/TDMP_A_1575652_F0007_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/dc05739db0a4/TDMP_A_1575652_F0008_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/5b43f8af330c/TDMP_A_1575652_F0009_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/cae0d2dbbfdc/TDMP_A_1575652_F0010_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/872c830d1d1c/TDMP_A_1575652_F0011_B.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d55e/6407582/8460629e57ad/TDMP_A_1575652_F0012_B.jpg

相似文献

1
Review of novel energetic polymers and binders - high energy propellant ingredients for the new space race.新型含能聚合物和黏合剂综述——新太空竞赛中的高能推进剂成分
Des Monomers Polym. 2019 Mar 1;22(1):54-65. doi: 10.1080/15685551.2019.1575652. eCollection 2019.
2
Performance and Kinetics Study of Self-Repairing Hydroxyl-Terminated Polybutadiene Binders Based on the Diels⁻Alder Reaction.基于狄尔斯-阿尔德反应的自修复端羟基聚丁二烯粘合剂的性能与动力学研究
Polymers (Basel). 2017 May 30;9(6):200. doi: 10.3390/polym9060200.
3
Energetic Polyoxetanes as High-Performance Binders for Energetic Composites: A Critical Review.作为含能复合材料高性能粘结剂的活性聚氧杂环丁烷：综述
Polymers (Basel). 2022 Nov 1;14(21):4651. doi: 10.3390/polym14214651.
4
Environmentally safe (chlorine-free): new green propellant formulation based on 2,2,2-trinitroethyl-formate and HTPB.环境安全（无氯）：基于2,2,2-三硝基乙基甲酸酯和端羟基聚丁二烯的新型绿色推进剂配方。
RSC Adv. 2018 Mar 27;8(21):11771-11777. doi: 10.1039/c8ra01515e. eCollection 2018 Mar 21.
5
Nitramine-Group-Containing Energetic Prepolymer: Synthesis, and Its Properties as a Binder for Propellant.含硝胺基团的含能预聚物：合成及其作为推进剂黏合剂的性能
Polymers (Basel). 2019 Nov 29;11(12):1966. doi: 10.3390/polym11121966.
6
Traditional vs. Energetic and Perchlorate vs. "Green": A Comparative Study of the Choice of Binders and Oxidising Agents.传统与含能及高氯酸盐与“绿色”：粘结剂和氧化剂选择的比较研究
Molecules. 2023 Jul 31;28(15):5787. doi: 10.3390/molecules28155787.
7
Dynamic Mechanical Response and Damage Mechanism of HTPB Propellant under Impact Loading.HTPB推进剂在冲击载荷下的动态力学响应及损伤机制
Materials (Basel). 2020 Jul 7;13(13):3031. doi: 10.3390/ma13133031.
8
Interaction Mechanism of Composite Propellant Components under Heating Conditions.复合推进剂组分在加热条件下的相互作用机理
Polymers (Basel). 2023 May 28;15(11):2485. doi: 10.3390/polym15112485.
9
Preparation and Characterization of Al/HTPB Composite for High Energetic Materials.用于高能材料的铝/端羟基聚丁二烯复合材料的制备与表征
Nanomaterials (Basel). 2020 Nov 8;10(11):2222. doi: 10.3390/nano10112222.
10
Enhancing Mechanical and Combustion Performance of Boron/Polymer Composites via Boron Particle Functionalization.通过硼颗粒功能化提高硼/聚合物复合材料的力学和燃烧性能
ACS Appl Mater Interfaces. 2021 Jun 23;13(24):28908-28915. doi: 10.1021/acsami.1c06727. Epub 2021 Jun 10.

引用本文的文献

1
Effect of Poly (Caprolactone) Introduction Site on the Network Structure and Properties of Glycidyl Azide Polymer Adhesive.聚己内酯引入位点对缩水甘油叠氮聚合物粘合剂网络结构及性能的影响
Polymers (Basel). 2025 Feb 28;17(5):661. doi: 10.3390/polym17050661.
2
Research on the Thermal Aging Performance of a GAP-Based Polyurethane Elastomer.基于GAP的聚氨酯弹性体热老化性能研究
Polymers (Basel). 2024 Mar 13;16(6):795. doi: 10.3390/polym16060795.
3
Study on Mechanical Properties and Failure Mechanisms of Highly Filled Hydroxy-Terminated Polybutadiene Propellant under Different Tensile Loading Conditions.

本文引用的文献

1
Synthesis of Energetic Nitrocarbamates from Polynitro Alcohols and Their Potential as High Energetic Oxidizers.
J Org Chem. 2015 Jun 19;80(12):6329-35. doi: 10.1021/acs.joc.5b00655. Epub 2015 Jun 4.
2
Tetranitroacetimidic acid: a high oxygen oxidizer and potential replacement for ammonium perchlorate.四硝基乙二酰胺：一种高氧氧化剂，有望替代高氯酸铵。
J Am Chem Soc. 2014 Aug 27;136(34):11934-7. doi: 10.1021/ja5074036. Epub 2014 Aug 14.
3
New roles for 1,1-diamino-2,2-dinitroethene (FOX-7): halogenated FOX-7 and azo-bis(diahaloFOX) as energetic materials and oxidizers.1,1-二氨基-2,2-二硝基乙烯（FOX-7）的新用途：卤代 FOX-7 和偶氮双（二卤代 FOX）作为含能材料和氧化剂。
不同拉伸载荷条件下高填充端羟基聚丁二烯推进剂力学性能及失效机理研究
Polymers (Basel). 2023 Sep 24;15(19):3869. doi: 10.3390/polym15193869.
4
Synthesis and Characterization of Random Block Hydroxyl-Terminated Polyfluoroether-Based Polyurethane Elastomers with Fluorine-Containing Side Chains.含氟侧链无规嵌段羟基封端聚氟醚基聚氨酯弹性体的合成与表征
Polymers (Basel). 2023 Jan 6;15(2):288. doi: 10.3390/polym15020288.
5
Promising Oxygen- and Nitrogen-Rich Azidonitramino Ether Plasticizers for Energetic Materials.用于含能材料的有前景的富氧富氮叠氮硝氨基醚增塑剂。
Molecules. 2022 Nov 10;27(22):7749. doi: 10.3390/molecules27227749.
6
New 5-Aminotetrazole-Based Energetic Polymers: Synthesis, Structure and Properties.新型基于5-氨基四唑的含能聚合物：合成、结构与性能
Materials (Basel). 2022 Oct 6;15(19):6936. doi: 10.3390/ma15196936.
7
Simple and Green Synthesis of a Novel Fluoro-Nitrato Energetic Plasticizer.新型氟代硝酸酯含能增塑剂的简易绿色合成
ACS Omega. 2022 Apr 13;7(16):14239-14243. doi: 10.1021/acsomega.2c00808. eCollection 2022 Apr 26.
8
Solid Propellant Formulations: A Review of Recent Progress and Utilized Components.固体推进剂配方：近期进展及所用组分综述
Materials (Basel). 2021 Nov 4;14(21):6657. doi: 10.3390/ma14216657.
9
Fluoropolymer/Glycidyl Azide Polymer (GAP) Block Copolyurethane as New Energetic Binders: Synthesis, Mechanical Properties, and Thermal Performance.含氟聚合物/缩水甘油叠氮聚合物（GAP）嵌段共聚氨酯作为新型含能粘合剂：合成、力学性能及热性能
Polymers (Basel). 2021 Aug 13;13(16):2706. doi: 10.3390/polym13162706.
10
Molecular dynamic simulation of performance of modified BAMO/AMMO copolymers and their effects on mechanical properties of energetic materials.改性BAMO/AMMO共聚物性能的分子动力学模拟及其对含能材料力学性能的影响
Sci Rep. 2020 Oct 23;10(1):18140. doi: 10.1038/s41598-020-75146-x.
J Am Chem Soc. 2013 Aug 14;135(32):11787-90. doi: 10.1021/ja406629g. Epub 2013 Aug 6.
4
Nitrotetrazolate-2N-oxides and the strategy of N-oxide introduction.硝替唑-2N-氧化物和 N-氧化物导入策略。
J Am Chem Soc. 2010 Dec 8;132(48):17216-26. doi: 10.1021/ja106892a. Epub 2010 Nov 11.
5
Thermal stability and kinetic of decomposition of nitrated HTPB.硝化 HTPB 的热稳定性和分解动力学。
J Hazard Mater. 2009 Dec 30;172(2-3):1659-64. doi: 10.1016/j.jhazmat.2009.08.040. Epub 2009 Aug 18.