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皮芯型智能调温纤维的制备与分析

Preparation and Analysis of Sheath-Core Intelligent Thermo-Regulating Fiber.

作者信息

Zhang Ronggen, Feng Pei, Yang Chongchang

机构信息

College of Mechanical Engineering, Donghua University, Shanghai 201620, China.

Engineering Research Center of Advanced Textile Machinery, Donghua University, Shanghai 201620, China.

出版信息

Polymers (Basel). 2022 Apr 20;14(9):1665. doi: 10.3390/polym14091665.

Abstract

In this work, a skin-core composite intelligent temperature-adjusting fiber was prepared using the composite melt spinning method, with polypropylene as the skin layer and T28-type paraffin as the core layer, in order to obtain clothing fibers with a bidirectional temperature adjustment function. A differential scanning calorimeter was used to test the phase-change latent heat of fibers with different amounts of paraffin injections, and an infrared thermal imager was used to monitor the skin-core composite intelligent temperature-adjusting fiber bundles and ordinary polypropylene fiber bundles under the same heating and cooling conditions. The temperature of the fiber bundle was considered to be a function of time. The results showed that with the increase in the amount of the paraffin injections, the proportion of the paraffin component in the fiber and the latent heat of the fiber phase transition also increased. When the paraffin injection amount was 1.5 mL/min, the melting enthalpy and the crystallization enthalpy reached 65.93 J/g and 66.15 J/g, respectively. Under the same conditions, the heating speed of the intelligent temperature-adjusting fiber bundle was found to be slower than that of the ordinary polypropylene fibers, and the maximum temperature difference between the two reached 8.0 °C. Further, the cooling speed of the former was also observed to be slower than that of the latter, and the maximum temperature difference between the two reached 6.7 °C.

摘要

在本工作中,采用复合熔融纺丝法制备了一种皮芯复合智能调温纤维,以聚丙烯为皮层,T28型石蜡为芯层,以获得具有双向调温功能的服装纤维。使用差示扫描量热仪测试不同石蜡注入量纤维的相变潜热,并使用红外热成像仪在相同的加热和冷却条件下监测皮芯复合智能调温纤维束和普通聚丙烯纤维束。纤维束的温度被视为时间的函数。结果表明,随着石蜡注入量的增加,纤维中石蜡成分的比例以及纤维相变潜热也增加。当石蜡注入量为1.5 mL/min时,熔融焓和结晶焓分别达到65.93 J/g和66.15 J/g。在相同条件下,发现智能调温纤维束的加热速度比普通聚丙烯纤维慢,两者之间的最大温差达到8.0℃。此外,还观察到前者的冷却速度也比后者慢,两者之间的最大温差达到6.7℃。

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