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两种典型胶粘剂作用下热老化对BFRP单搭接接头失效的影响

Influence of Hydrothermal Aging under Two Typical Adhesives on the Failure of BFRP Single Lap Joint.

作者信息

Fan Yisa, Liu Zhen, Zhao Gejin, Liu Jigao, Liu Yahui, Shangguan Linjian

机构信息

School of Mechanical Engineering, North China University of Water Resources and Electric Power, Zhengzhou 450045, China.

出版信息

Polymers (Basel). 2022 Apr 22;14(9):1721. doi: 10.3390/polym14091721.

Abstract

Facing increasingly serious resource crises, energy conservation is becoming the development trend of various delivery vehicles, and lightweight is an important way to achieve energy conservation. In this paper, the basalt fiber-reinforced resin composite material (BFRP) was selected to study the effect of its bonding structure, and it was used to make BFRP-BFRP joints. Two adhesives, Araldite2012 and Araldite2015, were used to make single-lap joints and dumbbell-shaped specimens. Aging environments of 80 °C/95% RH and 80 °C/pure water were used for the 0-day (unageing), 10-day, 20-day, and 30-day aging tests, respectively. According to Fick's second law, the moisture absorption change model of two adhesives was established, and it was found that the water absorption process could be divided into two stages, which explains the precipitation of water molecules and the reaction of water molecules with functional groups. The maximum average failure load and load-displacement curves under different environments and different joints were obtained by using the electronic universal tensile machine, and the exposure time was more important than the effect of humidity. At the same time, the change law of failure strength and ductility were analyzed. The change of T (Glass transition temperature) was analyzed by differential scanning calorimetry (DSC) equipment, and the results showed that molecular chain rupture was the reason for the decrease of T. It could be seen from the joint failure mode distribution that Araldite2012 adhesive was easily affected by the environment, and the joint of Araldite2015 adhesive was affected by the combined effect of the adhesive and BFRP.

摘要

面对日益严峻的资源危机,节能正成为各类运载工具的发展趋势,轻量化是实现节能的重要途径。本文选用玄武岩纤维增强树脂复合材料(BFRP)研究其粘结结构的影响,并制作BFRP-BFRP接头。使用两种胶粘剂Araldite2012和Araldite2015制作单搭接接头和哑铃形试件。分别在80℃/95%相对湿度和80℃/纯水的老化环境下进行0天(未老化)、10天、20天和30天的老化试验。根据菲克第二定律,建立了两种胶粘剂的吸湿变化模型,发现吸湿过程可分为两个阶段,这解释了水分子的析出以及水分子与官能团的反应。通过电子万能拉伸机获得不同环境和不同接头下的最大平均破坏载荷和载荷-位移曲线,发现暴露时间比湿度的影响更重要。同时,分析了破坏强度和延性的变化规律。利用差示扫描量热仪(DSC)设备分析了T(玻璃化转变温度)的变化,结果表明分子链断裂是T降低的原因。从接头破坏模式分布可以看出,Araldite2012胶粘剂容易受到环境影响,Araldite2015胶粘剂的接头受到胶粘剂和BFRP共同作用的影响。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9dea/9101458/d36ef4f70829/polymers-14-01721-g001.jpg

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