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多功能 C@FeO-MoO-rGO 三元复合材料的简便合成及其作为声敏吸附剂改善三苯甲烷纺织染料和作为超级电容器应用的潜在电极的多功能作用。

Facile synthesis of multifunctional C@FeO-MoO-rGO ternary composite and its versatile roles as sonoadsorbent to ameliorate triphenylmethane textile dye and as potential electrode for supercapacitor applications.

机构信息

Nanotechnology & Catalysis Research Centre (NANOCAT), Institute for Advanced Studies (IAS), University of Malaya (UM), Level 3, Block A, 50603, Kuala Lumpur, Malaysia.

Nanotechnology & Catalysis Research Centre (NANOCAT), Institute for Advanced Studies (IAS), University of Malaya (UM), Level 3, Block A, 50603, Kuala Lumpur, Malaysia.

出版信息

Environ Res. 2022 Sep;212(Pt C):113417. doi: 10.1016/j.envres.2022.113417. Epub 2022 May 13.

DOI:10.1016/j.envres.2022.113417
PMID:35569532
Abstract

The toxic wastewater effluents from textile dyes have been a significant environmental threat worldwide in recent decades. Against this backdrop, this study investigates the performance of C@FeO-MoO-rGO as a sonoadsorbent to ameliorate crystal violet (CV) dye from the aqua matrix and further explores its potential as an electrode in supercapacitor applications. The phase purity, crystal structure, surface morphology, thermal stability and magnetic behaviour characteristics of the composite were studied using various characterisation techniques such as powder X-ray diffraction (XRD), Raman Spectroscopy, Fourier transform infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), High-resolution transmission electron microscopy (HRTEM), Thermogravimetric analysis (TGA) and Vibrating-sample magnetometry (VSM). From the Langmuir isotherm model, the synthesised sonoadsorbent exhibited a maximum adsorption capacity of 1664.26 mg/g for crystal violet, which is remarkably high. Further, to its inherited magnetic characteristics, the composite can be easily separated from the solution by using an external magnet. Furthermore, the working electrode was synthesised with 80% active material, 10% carbon black, and 10% polyvinylidene difluoride to investigate its suitability in supercapacitor applications. The C@FeO-MoO-rGO composite exhibited an excellent capacitance value of 180.36 F/g with commendable cycling stability, making it suitable as a potential cathode material for the next generation supercapacitors.

摘要

在最近几十年,纺织染料产生的有毒废水排放已成为全球范围内的一个重大环境威胁。有鉴于此,本研究调查了 C@FeO-MoO-rGO 作为声吸附剂的性能,以改善水溶液中的结晶紫 (CV) 染料,并进一步探索其作为超级电容器应用中电极的潜力。使用各种特性分析技术,如粉末 X 射线衍射 (XRD)、拉曼光谱、傅里叶变换红外光谱 (FTIR)、场发射扫描电子显微镜 (FESEM)、高分辨率透射电子显微镜 (HRTEM)、热重分析 (TGA) 和振动样品磁强计 (VSM) 研究了复合材料的相纯度、晶体结构、表面形态、热稳定性和磁性特征。从朗缪尔等温模型可知,所合成的声吸附剂对结晶紫的最大吸附容量为 1664.26mg/g,这是非常高的。此外,由于其固有的磁性特征,复合材料可以通过使用外部磁铁从溶液中轻松分离。此外,以 80%的活性材料、10%的炭黑和 10%的聚偏二氟乙烯合成工作电极,以研究其在超级电容器应用中的适用性。C@FeO-MoO-rGO 复合材料表现出卓越的电容值 180.36F/g,具有令人称赞的循环稳定性,因此适合作为下一代超级电容器的潜在阴极材料。

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