Biroli Giulio, Charbonneau Patrick, Folena Giampaolo, Hu Yi, Zamponi Francesco
Laboratoire de Physique de l'Ecole Normale Supérieure, ENS, Université PSL, CNRS, Sorbonne Université, Université de Paris, F-75005 Paris, France.
Department of Chemistry, Duke University, Durham, North Carolina 27708, USA.
Phys Rev Lett. 2022 Apr 29;128(17):175501. doi: 10.1103/PhysRevLett.128.175501.
We study the local dynamical fluctuations in glass-forming models of particles embedded in d-dimensional space, in the mean-field limit of d→∞. Our analytical calculation reveals that single-particle observables, such as squared particle displacements, display divergent fluctuations around the dynamical (or mode-coupling) transition, due to the emergence of nontrivial correlations between displacements along different directions. This effect notably gives rise to a divergent non-Gaussian parameter, α_{2}. The d→∞ local dynamics therefore becomes quite rich upon approaching the glass transition. The finite-d remnant of this phenomenon further provides a long sought-after, first-principle explanation for the growth of α_{2} around the glass transition that is not based on multiparticle correlations.
我们研究了嵌入d维空间的粒子的玻璃形成模型中的局部动力学涨落,处于d→∞的平均场极限下。我们的解析计算表明,单粒子可观测量,如粒子位移平方,在动力学(或模式耦合)转变附近显示出发散的涨落,这是由于沿不同方向的位移之间出现了非平凡的相关性。这种效应显著地导致了一个发散的非高斯参数α₂。因此,在接近玻璃转变时,d→∞的局部动力学变得相当丰富。这种现象在有限d时的残余进一步为玻璃转变附近α₂的增长提供了一个长期寻求的、基于第一性原理的解释,该解释不基于多粒子相关性。