Yun Ruirui, Li Tuanhui, Zhang Beibei, He Lei, Liu Shoujie, Yu Can, Chen Zheng, Luo Shizhong
Anhui Laboratory of Molecule-Based Materials, Anhui Carbon Neutrality Engineering Center, College of Chemistry and Materials Science, Anhui Normal University, Wuhu 214001, P. R. China.
Institute of High Energy Physics, Chinese Academy of Science, Beijing 100049, P. R. China.
Chem Commun (Camb). 2022 Jun 8;58(46):6602-6605. doi: 10.1039/d2cc01941h.
Herein, a novel strategy has been proposed to design a hollow structure post-modified N sites coordinating to metal species. As a result, an atomically dispersed Co site catalyst with high loading has been obtained and has shown superb performance in CO cycloaddition to ethylene carbonate. This novel avenue can be extended to other atomically dispersed metal catalysts with high loading.
