Shi Yonggang, Yang Zhishuai, Liu Huaqing, Li Zijian, Tian Yukui, Wang Feng
Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China.
ACS Macro Lett. 2015 Jan 20;4(1):6-10. doi: 10.1021/mz500659f. Epub 2014 Dec 10.
Mechanically linked poly[2]rotaxanes have been successfully constructed via the hierarchical self-assembly strategy. The integration of two noninterfering noncovalent recognition motifs facilitates chain extension of the B21C7-based [2]rotaxane monomer, demonstrating the capabilities to form self-standing films with preferable transparency and softness.
通过分级自组装策略成功构建了机械连接的聚[2]轮烷。两个互不干扰的非共价识别基序的整合促进了基于B21C7的[2]轮烷单体的链延伸，证明了形成具有良好透明度和柔软性的自立膜的能力。
