Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610041, China.
University of Chinese Academy of Sciences, Beijing, 100049, China.
Angew Chem Int Ed Engl. 2022 Jul 25;61(30):e202205493. doi: 10.1002/anie.202205493. Epub 2022 Jun 13.
Activated by multiple consecutive oxidative radical-polar crossover and desaturation processes, the selective diamination of arylcyclobutanes, which is difficult to perform by classical metallonitrene C-H insertion, was achieved in a short time by rhodium(II) catalysis using N-fluorobenzenesulfonimide (NFSI) as the oxidant and nitrogen source.
通过多次连续的氧化自由基极性交叉和去饱和过程，芳基环丁烷的选择性二胺化反应得以实现，这是通过经典的金属亚氮化物 C-H 插入难以完成的。该反应在铑（II）催化下，使用 N-氟代苯磺酰胺（NFSI）作为氧化剂和氮源，在短时间内完成。
