钯催化二芳基甲醇衍生物与二硼甲烷的交叉偶联反应
Palladium-Catalyzed Cross-Coupling Reaction of Diarylmethanol Derivatives with Diborylmethane.
作者信息
Asai Kento, Miura Masahiro, Hirano Koji
机构信息
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, Suita, Osaka 565-0871, Japan.
出版信息
J Org Chem. 2022 Jun 3;87(11):7436-7445. doi: 10.1021/acs.joc.2c00715. Epub 2022 May 24.
PMID:35608528
Abstract
A palladium-catalyzed cross-coupling reaction of diarylmethanol derivatives with diborylmethane has been developed. The reaction proceeds chemoselectively to deliver the corresponding homobenzylic boronates in good yields.
摘要
已开发出一种钯催化的二芳基甲醇衍生物与二硼甲烷的交叉偶联反应。该反应具有化学选择性，能以良好的产率得到相应的高苄基硼酸酯。
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