关于1,3 - 二甲基胸腺嘧啶和胸腺嘧啶核苷环氧化物与亲核试剂的交叉偶联反应。
On the cross-coupling reaction of 1,3-dimethylthymine and thymidine epoxides with nucleophiles.
作者信息
Harayama T, Yanada R, Iio K, Yoneda F
出版信息
Nucleic Acids Symp Ser. 1986(17):25-8.
PMID:3562270
Abstract
Solvent effect in reaction of 1,3-dimethylthymine epoxide (1) with amines was investigated. The results are summarized in Table I, indicating that the ratio of formation of the cis product (2) increases as a solvent becomes more polar. Reaction of thymidine epoxide (5) with nucleophiles was also examined.
摘要
研究了1,3 - 二甲基胸腺嘧啶环氧化物（1）与胺反应中的溶剂效应。结果总结在表I中，表明随着溶剂极性增强，顺式产物（2）的生成比例增加。还研究了胸腺嘧啶核苷环氧化物（5）与亲核试剂的反应。
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