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基于铜纳米线电极的高拉伸性电致发光器件。

Highly stretchable electroluminescent device based on copper nanowires electrode.

作者信息

Tran Phuong, Tran Nguyen-Hung, Lee Ji-Hoon

机构信息

Division of Electronics Engineering, Future Semiconductor Convergence Technology Research Center, Jeonbuk National University, Jeonju, 54896, Korea.

出版信息

Sci Rep. 2022 May 27;12(1):8967. doi: 10.1038/s41598-022-13167-4.

DOI:10.1038/s41598-022-13167-4
PMID:35624312
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9142487/
Abstract

Although stretchable electroluminescent (EL) devices have been the research hotspots for decades because of their enormous market value in lighting sources and displays, fabrication of the stretchable EL device through a simple, cost-effective, and scalable method still remains an open issue. Here, a novel all solution-processed method is developed to fabricate a high-performance alternative current electroluminescent (ACEL) device based on copper nanowires (Cu NWs). The Cu NW-based electrode exhibited a low resistance change of less than 10% after 1000 stretching cycles at a tensile strain of 30% and the resistance variation of the electrode in one stretching-releasing cycle was less than 1% at the 1000th. To substantiate suitability for the wearable application, the ACEL device was stretched at a tensile strain of 100% and it retained a luminance of 97.6 cd/m. Furthermore, the device works well under different deformations such as bending, folding, rolling, and twisting. To the best of our knowledge, this is the first demonstration of Cu NWs applied in a stretchable ACEL, promising cost-effective electrode materials for various wearable electronics applications.

摘要

尽管可拉伸电致发光(EL)器件由于其在光源和显示器方面的巨大市场价值,几十年来一直是研究热点,但通过简单、经济高效且可扩展的方法制造可拉伸EL器件仍然是一个未解决的问题。在此,开发了一种新颖的全溶液处理方法,以制造基于铜纳米线(Cu NWs)的高性能交流电致发光(ACEL)器件。基于Cu NWs的电极在30%拉伸应变下经过1000次拉伸循环后,电阻变化小于10%,在第1000次循环时,电极在一个拉伸-释放循环中的电阻变化小于1%。为了证实其适用于可穿戴应用,ACEL器件在100%拉伸应变下进行拉伸,其亮度保持在97.6 cd/m²。此外,该器件在弯曲、折叠、卷曲和扭转等不同变形下均能正常工作。据我们所知,这是首次展示Cu NWs应用于可拉伸ACEL,有望成为各种可穿戴电子应用中具有成本效益的电极材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/6bcb9bc22bac/41598_2022_13167_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/bca3f2ee645a/41598_2022_13167_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/f9fa2d2f8560/41598_2022_13167_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/94308ab62df7/41598_2022_13167_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/258c1183385f/41598_2022_13167_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/ab00260e1406/41598_2022_13167_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/52a9dddd4563/41598_2022_13167_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/6bcb9bc22bac/41598_2022_13167_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/bca3f2ee645a/41598_2022_13167_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/f9fa2d2f8560/41598_2022_13167_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/94308ab62df7/41598_2022_13167_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/258c1183385f/41598_2022_13167_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/ab00260e1406/41598_2022_13167_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/52a9dddd4563/41598_2022_13167_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e86/9142487/6bcb9bc22bac/41598_2022_13167_Fig7_HTML.jpg

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Patterned, Flexible, and Stretchable Silver Nanowire/Polymer Composite Films as Transparent Conductive Electrodes.
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