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老化过程对添加橡胶碎屑的减压渣油氧化产物特性的影响。

Aging Process Effects on the Characteristics of Vacuum Residue Oxidation Products with the Addition of Crumb Rubber.

机构信息

Faculty of Chemistry and Chemical Technology, Al-Farabi Kazakh National University, 71, Al-Farabi Pr., Almaty 050040, Kazakhstan.

Institute of Combustion Problems, 172, Bogenbaibatyr Str., Almaty 050012, Kazakhstan.

出版信息

Molecules. 2022 May 20;27(10):3284. doi: 10.3390/molecules27103284.

Abstract

This paper considers the effect of aging processes on viscoelastic characteristics of vacuum residue oxidation products modified with crumb rubber. Viscoelastic properties were compared to original bitumen raw material-vacuum residue and vacuum residue oxidation products during short-term and long-term aging. The complex shear modulus of the vacuum residue and its oxidation products decreased with an increase in temperature. Short-term aging resulted in increased shear modulus for all samples.The vacuum residue oxidation product modified with crumb rubber had the maximum values of the rutting parameter and fatigue parameter. There was an expansion of the temperature range of plasticity: for the vacuum residue oxidation product with crumb rubber, its value was 67.2 °C. The curves of the black diagram of the modified vacuum residue oxidation product are shifted towards smaller phase angles with the increase in the shear modulus, which indicates the increase in the stiffness and elasticity of the rubber bitumen binders. The vacuum residue oxidation product modified with crumb rubber corresponded to the rubber bitumen binder of the grade RBB 60/90, according to its physical and mechanical indicators.

摘要

本文研究了老化过程对胶粉改性减压渣油氧化产物粘弹性特性的影响。在短期和长期老化过程中,比较了粘弹性特性与原始沥青原料——减压渣油和减压渣油氧化产物的差异。减压渣油及其氧化产物的复数剪切模量随温度升高而降低。短期老化导致所有样品的剪切模量都增加。胶粉改性减压渣油氧化产物的车辙参数和疲劳参数值最大。塑性温度范围扩大:对于胶粉改性减压渣油氧化产物,其值为 67.2°C。随着剪切模量的增加,改性减压渣油氧化产物的黑色图曲线向较小的相位角移动,表明橡胶沥青结合料的刚性和弹性增加。根据其物理力学指标,胶粉改性减压渣油氧化产物相当于 RBB 60/90 级橡胶沥青结合料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d823/9144889/05dc76cb9a13/molecules-27-03284-g001.jpg

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