Le Van Su, Nguyen Van Vu, Sharko Artem, Ercoli Roberto, Nguyen Thang Xiem, Tran Doan Hung, Łoś Piotr, Buczkowska Katarzyna Ewa, Mitura Stanisław, Špirek Tomáš, Louda Petr
Department of Material Science, Faculty of Mechanical Engineering, Technical University of Liberec, Studentska 2, 461 17 Liberec, Czech Republic.
Department of Pure and Applied Sciences, University of Urbino, Via Ca' Le Suore 2/4, 61029 Urbino, Italy.
Polymers (Basel). 2022 May 11;14(10):1945. doi: 10.3390/polym14101945.
Geopolymer foams are excellent materials in terms of mechanical loads and fire resistance applications. This study investigated the foaming process of geopolymers and foam stability, with a focus on the fire resistance performance when using polystyrene as the base layer. The main purpose is to define the influence of porosity on the physical properties and consequently to find applications and effectiveness of geopolymers. In this study, lightweight materials are obtained through a process called geopolymerization. Foaming was done by adding aluminum powder at the end of the geopolymer mortar preparation. The interaction between the aluminum powder and the alkaline solution (used for the binder during the mixing process) at room temperature is reactive enough to develop hydrogen-rich bubbles that increase the viscosity and promote the consolidation of geopolymers. The basic principle of thermodynamic reactions responsible for the formation of foams is characterized by hydrogen-rich gas generation, which is then trapped in the molecular structure of geopolymers. The geopolymer foams in this study are highly porous and robust materials. Moreover, the porosity distribution is very homogeneous. Experimental assessments were performed on four specimens to determine the density, porosity, mechanical strength, and thermal conductivity. The results showed that our geopolymer foams layered on polystyrene boards (with optimal thickness) have the highest fire resistance performance among others. This combination could withstand temperatures of up to 800 °C for more than 15 min without the temperature rising on the insulated side. Results of the best-performing geopolymer foam underline the technical characteristics of the material, with an average apparent density of 1 g/cm, a volume porosity of 55%, a thermal conductivity of 0.25 W/mK, and excellent fire resistance.
地质聚合物泡沫在机械负载和耐火应用方面是优异的材料。本研究调查了地质聚合物的发泡过程和泡沫稳定性,重点关注以聚苯乙烯为基层时的耐火性能。主要目的是确定孔隙率对物理性能的影响,从而找到地质聚合物的应用和有效性。在本研究中,通过一种称为地质聚合的过程获得轻质材料。发泡是在地质聚合物砂浆制备结束时添加铝粉来完成的。铝粉与碱性溶液(在混合过程中用作粘结剂)在室温下的相互作用具有足够的反应活性,能够产生富含氢气的气泡,这些气泡会增加粘度并促进地质聚合物的固结。负责形成泡沫的热力学反应的基本原理的特征是产生富含氢气的气体,然后这些气体被困在地质聚合物的分子结构中。本研究中的地质聚合物泡沫是高度多孔且坚固的材料。此外,孔隙率分布非常均匀。对四个试样进行了实验评估,以确定密度、孔隙率、机械强度和热导率。结果表明,我们层叠在聚苯乙烯板上(具有最佳厚度)的地质聚合物泡沫具有最高的耐火性能。这种组合能够在高达800°C的温度下承受超过15分钟,而隔热侧的温度不会升高。性能最佳的地质聚合物泡沫的结果突出了该材料的技术特性,其平均表观密度为1 g/cm,体积孔隙率为55%,热导率为0.25 W/mK,并且具有出色的耐火性。