Circularly Polarized Luminescent Triptycene-Based Polymers.

A series of chiral fluorescent polymers containing optically active triptycene units in the main chain were synthesized via Sonogashira-Hagihara coupling copolymerizations of (,)- or (,)-2,6-diethynyltriptycene with a range of diiodoaryls. Their optical and chiroptical properties were investigated under various solution conditions. We observe that these polymers emitted circularly polarized light owing to the chiral triptycene framework with a handed twisted rigid structure, and the fluorescence colors could be tuned in the whole visible range from blue to red by replacing the achiral comonomer units. They possessed luminescence dissymmetry factors of approximately 1.0 × 10, regardless of the incorporated comonomer units.